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多尺度Ti2AlC/TiAl复合材料的制备、显微组织及高温强化机理(英文)

Fabrication, microstructure and high-temperature strengthening mechanism of multi-scale Ti2AlC/TiAl composite

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【作者】 邓哲柳培张志勇王爱琴谢敬佩王振博

【Author】 Zhe DENG;Pei LIU;Zhi-yong ZHANG;Ai-qin WANG;Jing-pei XIE;Zhen-bo WANG;College of Materials Science and Engineering, Henan University of Science and Technology;State Key Laboratory of Advanced Casting Technologies;Provincial and Ministerial Co-construction of Collaborative Innovation Center for Non-ferrous Metal New Materials and Advanced Processing Technology;

【通讯作者】 柳培;张志勇;

【机构】 河南科技大学材料科学与工程学院高端装备铸造技术全国重点实验室有色金属新材料与先进加工技术省部共建协同创新中心

【摘要】 采用真空电弧熔炼制备了多尺度Ti2AlC/TiAl复合材料。微观结构表明,在全片层TiAl基体的晶界处原位析出微米级Ti2AlC颗粒。通过热处理工艺,微纳米级Ti2AlC在层片状TiAl/Ti3Al相界处定向析出,同时,纳米级Ti2AlC在TiAl晶内定向析出。当石墨粉的添加量为2%(摩尔分数)时,复合材料展现出最优的高温拉伸性能,抗拉强度达到561 MPa,伸长率为3.6%。结果表明,多尺度Ti2Al C在提高材料性能方面发挥多重协同效应:微米级Ti2AlC可以有效抑制晶界软化并阻碍位错运动,微纳米级Ti2AlC则能够阻止孪晶扩展并阻碍位错运动,纳米级Ti2AlC不仅能阻碍位错运动,还能细化层片状显微组织。

【Abstract】 The multi-scale Ti2 AlC/TiAl composites were fabricated. Micro-Ti2 AlC particles are obtained in-situ at the grain boundaries of the full lamellar TiAl matrix by vacuum arc melting. The targeted precipitation of submicro-Ti2 Al C at the lamellae TiAl/Ti3 Al phase boundary and directional precipitation of nano-Ti2 AlC within TiAl crystals are achieved by heat treatment. And the best high-temperature tensile properties are obtained when the graphite powder is added at 2 at.%, resulting in a tensile strength of 561 MPa and an elongation of 3.6%. These findings underscore the multifaceted role played by the multi-scale Ti2 AlC: micro-Ti2 AlC effectively inhibits grain boundary softening and hinders dislocation motion, while submicro-Ti2 AlC prevents twin propagation and obstructs dislocation motion. Nano-Ti2 AlC, on the other hand, not only hinders dislocation movement but also fine-tunes the lamellar microstructure.

【基金】 financially supported by the Open Research Fund of State Key Laboratory of Advanced Casting Technologies, China (No. CAT2023-007);Key Research and Development Program in Henan Province, China (No. 242102230059);the National Natural Science Foundation of China (No. 52101174)
  • 【文献出处】 Transactions of Nonferrous Metals Society of China ,中国有色金属学报(英文版) , 编辑部邮箱 ,2026年04期
  • 【分类号】TB33;TG156
  • 【下载频次】136
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