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废纺织物预处理工艺对纤维增强回收塑料结构与性能的影响

Effects of pretreatment processes for waste textiles on the structure and properties of fiber-reinforced recycled plastics

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【作者】 徐龙吴伟强杨松伟周为明曹长林谢一督杨艺林陈庆华钱庆荣

【Author】 XU Long;WU Weiqiang;YANG Songwei;ZHOU Weiming;CAO Changlin;XIE Yidu;YANG Yilin;CHEN Qinghua;QIAN Qingrong;College of Environmental Science and Engineering, Fujian Normal University; Engineering Research Center of Polymer Green Recycling, Ministry of Education; Fujian Provincial Key Laboratory of Pollution Control &Resource Reuse;Quangang Petrochemical Research Institute, Fujian Normal University;Fujian Nan’an Shida Rubber & Plastic Machinery Co., Ltd.;

【通讯作者】 曹长林;

【机构】 福建师范大学环境与资源学院,聚合物资源绿色循环利用教育部工程研究中心,福建省污染控制与资源循环利用重点实验室福建师范大学泉港石化研究院福建南安实达橡塑机械有限公司

【摘要】 以废纺织物、回收塑料(瓶盖)为原料,通过切断、开松和预包覆等对废纺织物进行了预处理,采用连续密炼挤出和注塑成型方法制备了纺织纤维增强塑料复合材料,并利用扫描电子显微镜(SEM)、旋转流变仪和万能拉伸试验机分析了废纺纤维预处理工艺对废纺纤维-回收塑料复合材料结构与性能的影响。结果表明:纤维形态显著影响复合材料性能,其中小块丝状纤维增强效果最佳,所得复合材料的拉伸强度和弯曲强度分别达到23.61 MPa和25.31 MPa,较未增强回收瓶盖基体分别提升23.87%和87.64%,较大块状纤维复合材料分别提高11.16%和8.44%。微观结构分析表明,适当的纤维尺寸控制可显著改善分散性,通过脱粘和拔出机制有效阻碍裂纹扩展。流变学研究表明,小块丝状纤维能够更好地形成稳定的纤维网络结构。

【Abstract】 This study utilized waste textiles and recycled plastics(bottle cap) as raw materials. The waste textiles were pretreated through cutting, opening, and pre-coating processes. Textile fiber-reinforced plastic composites were prepared using continuous internal mixing extrusion and injection molding methods. The effects of pretreatment techniques on the structure and properties of the waste textile fiber/recycled plastic composites were investigated by scanning electron microscopy, rotational rheometry, and universal tensile testing. The results demonstrated that fiber morphology significantly influences composite performance, with small flake-shaped fibers exhibiting the most pronounced reinforcement effect. The resulting composites achieved tensile and flexural strengths of 23.61 MPa and 25.31 MPa, respectively, representing 23.87% and 87.64% improvements over the unreinforced recycled bottle cap matrix, and 11.16% and 8.44% enhancements compared to composites containing larger fiber fragments. Microstructural analysis revealed that appropriate fiber size control significantly improves dispersion, effectively hindering crack propagation through debonding and pull-out mechanisms. Rheological studies indicated that small flake-shaped fibers facilitate the formation of a more stable fiber network structure, endowing the composite with superior dynamic mechanical response.

【基金】 国家重点研发计划(2023YFC3906300);福州市“揭榜挂帅”科技重大项目(2023-ZD-005)
  • 【文献出处】 再生资源与循环经济 ,Recyclable Resources and Circular Economy , 编辑部邮箱 ,2026年05期
  • 【分类号】X705
  • 【下载频次】8
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