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新型纸基除湿材料的制备及其性能研究

Preparation and Properties of a Novel Paper-based Desiccant Material

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【作者】 卢志锋徐桂龙唐敏宋强梁云

【Author】 LU Zhifeng;XU Guilong;TANG Min;SONG Qiang;LIANG Yun;School of Light Industry and Engineering,South China University of Technology;National Engineering Research Center of Papermaking and Pollution Control,South China University of Technology;

【通讯作者】 徐桂龙;

【机构】 华南理工大学轻工科学与工程学院华南理工大学造纸与污染控制国家工程研究中心

【摘要】 本研究以竹浆、玻璃纤维和双熔点聚对苯二甲酸乙二醇酯(PET)纤维为原料,采用湿法成形工艺制备多孔纤维基材,并通过浸渍法负载聚丙烯酸钠(PAAS)树脂,开发出一种新型纸基除湿材料。系统研究了纤维配比、热压时间及PAAS树脂留着量对材料结构与性能的影响。结果表明,按照竹浆、双熔点PET纤维、短切玻纤质量比=4∶3∶3进行抄造,92℃热压8 min,PAAS树脂留着量为140%时,所得纸基除湿材料综合性能最佳,其抗张指数为29.5 N·m/g,挺度为1.22 mN·m,耐破度为149 kPa;在30℃、相对湿度90%环境下的平衡吸湿率为76%,吸湿后纸基除湿材料的抗张指数、挺度、耐破度分别保持在7.44 N·m/g、0.70 mN·m、149 kPa,并表现出良好的低温放湿特性。经过50次吸放湿循环后,材料吸湿容量基本保持不变,显示出良好循环稳定性。

【Abstract】 This study presented a novel paper-based desiccant material fabricated through a wet-forming process. A porous fibrous substrate was first prepared from bamboo pulp, glass fibers, and dual-melting-point polyethylene terephthalate(PET) fibers, and then impregnated with sodium polyacrylate(PAAS) resin. The effects of fiber composition, hot-pressing time, and PAAS retention on the material’s structure and properties were systematically investigated. Results showed that the optimal performance was achieved with a mass ratio of 4∶3∶3 for the dual-melting-point PET fibers, bamboo pulp, and chopped glass fibers, respectively, after hot-pressing at 92 ℃ for 8 min and with a resin re??tention of 140%, exhibited optimal overall performance. Its tensile index was 29.5 N·m/g, stiffness 1.22 mN·m, and burst strength 149 kPa. Under conditions of 30 ℃ and 90% relative humidity(RH), the equilibrium moisture absorption rate reached 76%. After moisture absorption, the tensile index, stiffness, and burst strength were maintained at 7.44 N·m/g, 0.70 mN·m, and 149 kPa, respectively, along with demonstrat??ing good low-temperature moisture release characteristics. Remarkably, its moisture absorption capacity remained virtually unchanged over 50 absorption-desorption cycles, indicating exceptional cycling stability.

【基金】 中央高校基本科研业务费专项资金
  • 【文献出处】 中国造纸 ,China Pulp & Paper , 编辑部邮箱 ,2026年05期
  • 【分类号】TS76
  • 【下载频次】28
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