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Al-10%RE(RE=Ce、Nd、Y、La)合金在典型海洋大气环境下的腐蚀行为研究

Corrosion Behavior of Al-10%RE(RE = Ce, Nd, Y, La) Alloys in Typical Marine Atmospheric Environments

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【作者】 谢睿蒋全通韩东晓陈烨刘万鹏裴炎彤段继周侯保荣

【Author】 XIE Rui;JIANG Quantong;HAN Dongxiao;CHEN Ye;LIU Wanpeng;PEI Yantong;DUAN Jizhou;HOU Baorong;School of Mechanical and Automotive Engineering,Qingdao University of Technology;Key Laboratory of Advanced Marine Materials,Institute of Oceanology,Chinese Academy of Sciences;Sanya Institute of Oceanology;Laoshan Laboratory;699 Factory,Second Research Academy,China Aerospace Science and Industry Corporation;

【通讯作者】 蒋全通;

【机构】 青岛理工大学机械与汽车工程学院中国科学院海洋研究所海洋关键材料全国重点实验室三亚海洋生态环境工程研究院崂山实验室中国航天科工集团第二研究院六九九厂

【摘要】 将二元稀土铝合金Al-10%RE(RE=Ce、Nd、Y、La,质量分数)在三亚和青岛2个大气腐蚀试验站进行了大气环境暴露试验。通过测量质量损失、观察腐蚀形貌、分析腐蚀产物和进行电化学测试等手段研究其在典型海洋大气环境下的腐蚀行为。结果表明,110 d的试验周期内,2个试验站的腐蚀速率关系是青岛>三亚,这可能与大气中SO2含量有关。4种铝合金腐蚀速率关系Al-10Nd > Al-10La > Al-10Y > Al-10Ce,这可能与其微观结构析出相的数量和分布有关。2个试验站的腐蚀都是以局部腐蚀为主,形成的腐蚀产物成分差别不明显,主要产物是Al2O3、AlO(OH)和Al(OH)3。此外,青岛站还生成了少量Al2(SO43。生成的腐蚀产物膜对腐蚀过程有一定影响,合金的保护能力会随着时间的推移而发生变化。

【Abstract】 The binary Al-alloy Al-10%RE(Ce, Nd, Y, La) was placed in two atmospheric corrosion test stations(Sanya and Qingdao) for the purpose of conducting atmospheric exposure tests. The corrosion behavior in typical marine atmospheric environments was studied by measuring mass loss, observing corrosion morphology, analyzing corrosion products and performing electrochemical tests. The findings demonstrated that the corrosion rate relationship between the two test stations was Qingdao > Sanya during the 110 d test cycle, which may be associated with the SO2 content in the atmosphere. And the corrosion rate relationship of the four binary aluminium alloys is Al-10 Nd > Al-10 La > Al-10Y > Al-10 Ce, which may be related to the number and distribution of their microstructural precipitated phases. The corrosion at the two test stations was mainly localized, and the composition of the corrosion products formed did not differ significantly, with the main products being Al2O3, AlO(OH) and Al(OH)3. In addition, a small amount of Al2(SO43 was generated at the Qingdao station. The corrosion product film that is generated exerts an effect on the corrosion process, and the protective ability of the alloy changes over time.

【基金】 山东省自然科学基金(ZR2024ME163);海南省崖州湾科技创新联合项目课题(2021CXLH0005);青岛海洋科学与技术国家实验室"问海计划"课题(2021WHZZB2301)~~
  • 【文献出处】 中国腐蚀与防护学报 ,Journal of Chinese Society for Corrosion and Protection , 编辑部邮箱 ,2026年02期
  • 【分类号】TG172.3
  • 【下载频次】88
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