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K2CO3对高磷鲕状赤铁矿球团氢还原-熔分过程的影响机理

Influence mechanism of K2CO3 on the hydrogen reduction and melting process of high-phosphorus oolitic hematite pellets

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【作者】 杨潮鑫赵一将黄记鹏马江华李光强

【Author】 YANG Chaoxin;ZHAO Yijiang;HUANG Jipeng;MA Jianghua;LI Guangqiang;State Key Laboratory of Advanced Refractories,Wuhan University of Science and Technology;Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education,Wuhan University of Science and Technology;Hubei Provincial Key Laboratory for New Processes of Ironmaking and Steelmaking,Wuhan University of Science and Technology;

【通讯作者】 李光强;

【机构】 武汉科技大学先进耐火材料全国重点实验室武汉科技大学钢铁冶金及资源利用省部共建教育部重点实验室武汉科技大学钢铁冶金新工艺湖北省重点实验室

【摘要】 本文研究了K2CO3对高磷鲕状赤铁矿氢还原过程的影响,通过热力学计算了氢气还原过程中脉石与含磷矿物赋存形态的变化。结果表明,添加K2CO3可以有效抑制铁铝尖晶石等相的产生,进而促进铁氧化物的还原。在添加K2CO3的基础上,再加入少量CaF2作为助熔剂可以进一步提高铁的熔分回收率,降低铁中磷含量。在复合添加8%K2CO3和4%CaF2的条件下,球团熔分后的金属产物铁回收率达到84.90%,P含量降至0.06%。

【Abstract】 This study investigated the effects of K2 CO3 on the hydrogen reduction process of high-phosphorus oolitic hematite,and the phase transformation behavior of gangue and phosphorus-bearing minerals during hydrogen reduction was analyzed through thermodynamic calculations. The results show that adding K2 CO3 effectively suppresses the formation of phases such as hercynite,thereby promoting the reduction of iron oxides. Furthermore,the introduction of a small amount of CaF2 as a flux further enhances the melting-separation recovery rate of iron and reduces the phosphorus content in the metal product. Under the condition of composite addition of 8% K2 CO3 and 4% CaF2,the iron recovery rate of the metal product after pellet melting-separation reached 84.90%,with the phosphorus content decreasing to 0.06%.

【基金】 国家自然科学基金(52274305)
  • 【文献出处】 武汉科技大学学报 ,Journal of Wuhan University of Science and Technology , 编辑部邮箱 ,2026年01期
  • 【分类号】TF046.6
  • 【下载频次】9
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