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Double Ionization to CO2 Produces Molecular Oxygen: A Roaming Mechanism

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【作者】 马启博郝鑫泰周家琪薛晓睿曾庆睿李鹏王磊任雪光

【Author】 Qibo Ma;Xintai Hao;Jiaqi Zhou;Xiaorui Xue;Qingrui Zeng;Peng Li;Lei Wang;Xueguang Ren;Ministry of Education Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter,School of Physics, Xi’an Jiaotong University;

【通讯作者】 周家琪;任雪光;

【机构】 Ministry of Education Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter,School of Physics, Xi’an Jiaotong University

【摘要】 <正>Abiotic oxygen formation predates photosynthesis,sustaining early chemical evolution,yet its elementary mechanisms remain contested.Here,we show the production pathways for molecular oxygen from doubly ionized carbon dioxide upon electron-impact.Through fragment ions and electron coincidence momentum imaging,we unambiguously determine the ionization mechanism by measuring the projectile energy loss in association withthe C++O2+channel.

【基金】 supported by the National Natural Science Foundation of China (Grant Nos. 12325406, 92261201, 12404305, and W2512072);the Shaanxi Province Natural Science Fundamental Research Project (Grant Nos. 2023JC-XJ-03 and23JSQ013);the China Postdoctoral Science Foundation (Grant Nos. BX20240286 and 2024M7625)
  • 【文献出处】 Chinese Physics Letters ,中国物理快报(英文版) , 编辑部邮箱 ,2026年01期
  • 【分类号】TQ116.14
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