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Ice-templated Aramid Nanofiber Aerogel-reinforced PTFE Composites for High-frequency Applications

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【作者】 王禹琴CHEN XianLI QiangzhiWU ZhangweiZHOU Jing沈杰陈文

【Author】 WANG Yuqin;CHEN Xian;LI Qiangzhi;WU Zhangwei;ZHOU Jing;SHEN Jie;CHEN Wen;Hubei Longzhong Laboratory,Wuhan University of Technology Xiangyang Demonstration Zone;State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,School of Materials Science and Engineering,Wuhan University of Technology;Sanya Science and Education Innovation Park,Wuhan University of Technology;

【通讯作者】 沈杰;陈文;

【机构】 Hubei Longzhong Laboratory,Wuhan University of Technology Xiangyang Demonstration ZoneState Key Laboratory of Advanced Technology for Materials Synthesis and Processing,School of Materials Science and Engineering,Wuhan University of TechnologySanya Science and Education Innovation Park,Wuhan University of Technology

【摘要】 We fabricated aramid nanofiber aerogels using ice-templated and freeze-dried method, and introduced them as a 3D filler framework in PTFE-based composites. Additionally, the deprotonation method was employed to introduce reactive groups on the aramid nanofiber aerogels’ surface, strengthening the interfacial bonding between the aramid nanofiber aerogels and the PTFE matrix. This interfacial modification strategy effectively improves the interfacial compatibility of the composites. As a result, the prepared composites exhibit remarkable tensile strength(36 MPa), a low coefficient of thermal expansion(55 ppm/°C), and excellent dielectric properties(dielectric constant(D_k 2.18), dielectric loss(D_f <0.003) at 10 GHz), making them highly suitable for high-frequency integrated devices.

【Abstract】 We fabricated aramid nanofiber aerogels using ice-templated and freeze-dried method, and introduced them as a 3D filler framework in PTFE-based composites. Additionally, the deprotonation method was employed to introduce reactive groups on the aramid nanofiber aerogels’ surface, strengthening the interfacial bonding between the aramid nanofiber aerogels and the PTFE matrix. This interfacial modification strategy effectively improves the interfacial compatibility of the composites. As a result, the prepared composites exhibit remarkable tensile strength(36 MPa), a low coefficient of thermal expansion(55 ppm/°C), and excellent dielectric properties(dielectric constant(D_k 2.18), dielectric loss(D_f <0.003) at 10 GHz), making them highly suitable for high-frequency integrated devices.

【基金】 supported by the Open Fund of Hubei Longzhong Laboratory (No.2024KF-04);the Chutian Talent Program Innovation Team;the Natural Science Foundation Innovation Research Team of Hainan Province (No. 524CXTD431)
  • 【文献出处】 Journal of Wuhan University of Technology(Materials Science) ,武汉理工大学学报(材料科学版)(英文版) , 编辑部邮箱 ,2026年03期
  • 【分类号】TB332
  • 【下载频次】4
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