【摘要】 生物质基平台分子氧化反应（BOR）代替析氧反应可以实现绿电制氢经济性和安全性双重提升，对我国早日实现“双碳”目标具有重要意义。钴基催化剂不仅在BOR中具有优异的催化性能，而且与贵金属基催化剂相比在储量和成本方面更具优势，因此受到广泛关注。总结了钴基催化剂表面反应机制及常见生物质基平台分子如葡萄糖、甘油和5-羟甲基糠醛的氧化反应途径，系统梳理适用于BOR的钴基催化剂合成方法及改性策略，着重介绍钴基催化剂在BOR中所展现出的构效关系，最后对钴基催化剂在BOR中的现状和未来发展进行了展望。更多还原

【Abstract】 The use of biomass-based platform molecules oxidation reaction(BOR) to replace oxygen evolution reaction can achieve both economic and safety improvement of green power for hydrogen production, which is important for China to achieve the goals of “carbon peaking” and “carbon neutrality” as soon as possible. Cobalt-based catalysts have received widespread attention not only for their excellent catalytic performance in BOR, but also for their advantages in terms of reserves and cost compared to noble metal-based catalysts. In this paper, the surface reaction mechanisms of cobalt-based catalysts and the oxidation reaction pathways of common biomass-based platform molecules such as glucose, glycerol,and 5-hydroxymethylfurfural are summarized. In addition, the synthesis methods and modification strategies of cobalt-based catalysts suitable for BOR have been systematically reviewed. Notably, the structurefunction relationship exhibited by cobalt-based catalysts in BOR is highlighted. Finally, the current status and future development of cobalt-based catalysts in BOR are prospected.更多还原