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拉曼光谱技术在纸质文物成分与结构分析研究中的进展

Component and Structural Analysis of Paper-Based Cultural Relics Based on Raman Spectroscopy Technology

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【作者】 郑冬青张高愿鲁钢陈建秋宋雅琴

【Author】 ZHENG Dongqing;ZHANG Gaoyuan;LU Gang;CHEN Jianqiu;SONG Yaqin;Nanjing Library;Key Lab of Paper Literatures Conservation in Neoteric and Modern China (Nanjing Museum);State Key Laboratory of Natural Medicines, China Pharmaceutical University;College of Materials Science and Engineering, Nanjing Tech University;

【通讯作者】 陈建秋;宋雅琴;

【机构】 南京图书馆纸质文物保护国家文物局重点科研基地(南京博物院)中国药科大学多靶标天然药物全国重点实验室南京工业大学材料科学与工程学院

【摘要】 纸质文物是人类文明的重要载体,但易受光照、虫害、霉菌等影响发生老化,其保护与修复意义重大,尤其是无损分析需求迫切。拉曼光谱凭借无损检测、高特异性、微区分析等优势,在纸质文物研究中应用广泛。本文综述其在纸质文物多方面的核心应用,对拉曼光谱在纸张原料成分与制作工艺认知、纸张颜料成分研究、纸质文物降解程度以及劣化机制现状进行了总结分析。同时,随着科技的发展,拉曼光谱与其他技术等的结合进一步丰富了拉曼光谱在纸质文物中的应用。文章结合文献指出了当前拉曼光谱存在数据库不足、基体干扰、灵敏度低等局限性,提出了便携式原位检测、动态监测等新发展方向,为纸质文物保护提供科学支撑。

【Abstract】 Paper-based cultural relics are vital carriers of human civilization, yet they are susceptible to aging due to factors such as light exposure, insect damage, and mold. Their protection and restoration are of great significance, particularly the urgent demand for non-destructive analysis. Raman spectroscopy, with its advantages of non-destructive detection, high specificity, and micro-area analysis, has been widely applied in the study of paper-based cultural relics. This paper reviews its core applications across multiple aspects of paper-based cultural relics, summarizing and analyzing the current status of Raman spectroscopy in understanding paper raw material composition and manufacturing techniques, studying pigment components on paper, assessing the degradation degree of paper-based relics, and elucidating deterioration mechanisms. Meanwhile, with technological advancements, the integration of Raman spectroscopy with other techniques has further enriched its applications in paper-based cultural relics. Drawing on the literature, the article highlights current limitations of Raman spectroscopy, including insufficient databases, matrix interference, and low sensitivity, and proposes new development directions such as portable in-situ detection and dynamic monitoring, providing scientific support for the conservation of paper-based cultural relics.

【基金】 国家文物局文物科学技术研究项目(2023ZCK015);纸质文物保护国家文物局重点科研基地及近现代纸质文献脱酸保护技术文化和旅游部重点实验室开放课题(NBKFKT0202)
  • 【文献出处】 光散射学报 ,The Journal of Light Scattering , 编辑部邮箱 ,2026年01期
  • 【分类号】O657.37;K87
  • 【下载频次】10
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