【摘要】 磺酰氟化合物因其独特的生物活性和化学反应性能而备受关注.磺酰氟官能团通常通过S—F键的构建来实现.近年来,随着点击化学概念的兴起,化学家们获得了一种全新的方法,能够利用“SO₂F”源试剂,直接在分子结构中引入磺酰氟官能团,从而兼顾反应的选择性与合成效率.本综述将对近年来开发的各类“SO₂F”源试剂及其在合成中的应用进行概述.更多还原

【Abstract】 Sulfonyl fluoride compounds have garnered significant attention due to their unique biological activity and reactivity. The sulfonyl fluoride functional group is typically introduced by constructing S—F bond. In recent years, the rise of the click chemistry concept has provided chemists with a novel approach, utilizing “SO₂F” reagents to directly introduce the sulfonyl fluoride functional group into molecular structures, balancing both reaction selectivity and synthetic efficiency. This review provides an overview of the synthesis and applications of various “SO₂F” reagents developed in recent years.更多还原