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Nd2O3在NaF-AlF3熔盐体系中的溶解度

Solubility of Nd2O3 in the NaF-AlF3 Molten Salt System

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【作者】 黄义鹏; 杨俊; 祁燈锐; 杨凤丽;

【Author】 HUANG Yi-peng;YANG Jun;QI Deng-rui;YANG Feng-li;School of Metallurgical Engineering, Jiangxi University of Science and Technology;

【通讯作者】 黄义鹏;

【机构】 江西理工大学冶金工程学院;

【摘要】 采用等温饱和法系统测定了Nd2O3在NaF-AlF3熔盐中的溶解度,重点考察了熔盐温度(1 010~1 070℃)和NaF/AlF3物质的量之比(2.0~2.6)对其溶解度的影响。通过实验数据拟合,建立了Nd2O3溶解度与熔盐温度和NaF/AlF3物质的量之比的一次回归模型。结果表明:Nd2O3在NaF-AlF3熔盐中溶解平衡时间不小于60 min;在NaF-AlF3熔盐体系中,Nd2O3溶解度随着熔盐温度升高和NaF/AlF3物质的量之比增加而明显增大;在熔盐温度1 070℃、NaF/AlF3物质的量之比2.6条件下,Nd2O3溶解度达到最大值6.20%;在实验参数范围内,构建的回归模型决定系数R2达0.983。

【Abstract】 The solubility of Nd2O3 in the NaF-AlF3 molten salt system was systematically determined using the isothermal saturation method, with a focus on the effects of molten salt temperature(1 010~1 070 ℃) and NaF/AlF3 molar ratio(2.0~2.6) on its solubility.A first-order regression model correlating the solubility of Nd2O3 with molten salt temperature and NaF/AlF3 molar ratio was established through experimental data fitting.The results demonstrate that the dissolution equilibrium of Nd2O3 in the NaF-AlF3 molten salt is achieved in no less than 60 min, and the solubility significantly increases with increasing molten salt temperature and higher NaF/AlF3 molar ratio.The solubility of Nd2O3 reaches a maximum value of 6.20% at 1 070 ℃ with a NaF/AlF3 molar ratio of 2.6.Within the experimental parameter range, the constructed regression model achieves a coefficient of determination(R2) of 0.983.

【基金】 江西省教育厅青年项目(GJJ2200876)
  • 【文献出处】 稀有金属与硬质合金 ,Rare Metals and Cemented Carbides , 编辑部邮箱 ,2025年05期
  • 【分类号】TF845
  • 【下载频次】16
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