【摘要】 在快速聚合过程中,实现一维（1D）多孔炭纳米棒的可控合成对其实际应用至关重要。本文报道了一种ID多孔炭纳米棒的制备方案:以棕榈酸钠和F127在质子化三聚氰胺的促进下组装形成的棒状胶束作为模板;随后,在该棒状胶束的导向下,制备出三聚氰胺基氮掺杂聚合物纳米棒,经炭化处理后得到相应的氮掺杂炭纳米棒。在三电极体系中,以所制氮掺杂炭纳米棒作为超级电容器电极材料时,在电流密度为0.2 A g^-1的条件下,比电容达301.66 F g^-1,比表面积归一化电容高达67.07μF cm^-2。氮掺杂特性和一维形貌赋予该炭纳米棒较低的内阻和良好的稳定性,使其不仅适用于基础研究,也能满足从材料化学到电化学储能等多个领域的实际应用需求。更多还原

【Abstract】 The ability to control the preparation of one-dimensional（1D） porous carbon nanorods,especially during rapid polymerization,is key to their practical application.We report a method for synthesizing 1D porous carbon nanorods,characterized by the formation of rod-like micelles that are assembled from sodium palmitate and Pluronic F127,facilitated by protonated melamine,and subsequently converted into melamine-based N-doped polymer nanorods which were carbonized to produce the corresponding N-doped carbon nanorods.The specific capacitance of the supercapacitor used the as-prepared N-doped nanorods as electrode material in a three-electrode system was calculated to be 301.66 F g^-1 at a current density of 0.2 A g^-1,with an ultra-high specific surface area normalized capacitance of up to 67.07 μF cm^-2.The N-doping and their one-dimensionality give the nanorods a low internal resistance and good stability,making them well suited for fundamental studies and practical applications ranging from materials chemistry to electrochemical energy storage.更多还原