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仙人掌状SnO2/ZnO纳米复合材料的制备及其对NO2的高灵敏快速检测

Synthesis of Cactus-Lke SnO2/ZnO Nanocrystals and Its Highly Sensitive and Rapid Detection of NO2

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【作者】 南宁; 王宇鹤; 于灵敏; 李春; 刘晓芬;

【Author】 NAN Ning;WANG Yuhe;YU Lingmin;LI Chun;LIU Xiaofen;School of Materials and Chemical Engineering, Xi’an Technological University;College of Chemical Engineering and Modern Materials, ShangLuo University;Research Centre of Grapheme Technology and Application, ShangLuo University;

【通讯作者】 于灵敏;

【机构】 西安工业大学材料与化工学院; 商洛学院化学工程与现代材料学院; 商洛学院商洛市石墨烯技术与应用研究中心;

【摘要】 为了解决纯SnO2基气体传感器对NO2灵敏度低、响应时间长的难题,本文采用水热法制备仙人掌状SnO2/ZnO纳米复合材料,研究了不同配比对SnO2/ZnO复合材料结构形貌与气敏性能的影响。研究结果表明:在水热反应温度180℃、时间6 h,煅烧温度500℃,时间3 h的条件下,SnO2/ZnO配比为35∶1时制得仙人掌状SnO2/ZnO纳米复合材料。NO2气敏特性结果显示,在工作温度300℃条件下,其对10 ppm NO2的响应值可达587.503,响应和恢复时间分别为5 s和39 s,较纯SnO2响应值提升了3.2倍,响应时间缩短了32 s。

【Abstract】 Pure SnO2-based gas sensors are low in sensitivity to NO2 and long in response time.In this study, the hydrothermal method was used to synthesize cactus-like SnO2/ZnO nanocomposites, the impacts of different ratios on their morphological structure and gas sensing performance were investigated.The results show that the cactus-like SnO2/ZnO nanocomposite was obtained under the conditions of the water-thermal reaction temperature of 180 °C for 6 hours, the calcination temperature of 500 °C for 3 hours, and the SnO2/ZnO ratio of 35:1.The NO2 gas sensing characteristics demonstrate that, at the operating temperature of 300 ℃, its response value to 10 ppm NO2 is 587.503 and its response time is 5 s and recovery time 39 s.Compared to pure SnO2,its response value increases by a factor of 3.2 and its response time reduces by 32 s.

【基金】 陕西省重点研发计划项目(2024GX-YBXM-321);商洛市工程中心平台项目(24KYZX02);商洛学院科研计划资助项目(20FK004);省级大学生创新创业训练计划项目(S202311396079)
  • 【文献出处】 西安工业大学学报 ,Journal of Xi’an Technological University , 编辑部邮箱 ,2025年01期
  • 【分类号】TP212;X831
  • 【下载频次】81
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