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Electric Field-Controlled Interfacial Polarization Coupling in van der Waals Ferroelectric Heterojunctions

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【作者】 李伟柳衡曾华凌

【Author】 Wei Li;HengLiu;Hualing Zeng;International Center for Quantum Design of Functional Materials, Hefei National Research Center for Physical Sciences at the Microscale, University of Science and Technology of China;Key Laboratory of Strongly Coupled Quantum Matter Physics, Department of Physics, Chinese Academy of Sciences,University of Science and Technology of China;Hefei National Laboratory, University of Science and Technology of China;

【通讯作者】 曾华凌;

【机构】 International Center for Quantum Design of Functional Materials, Hefei National Research Center for Physical Sciences at the Microscale, University of Science and Technology of ChinaKey Laboratory of Strongly Coupled Quantum Matter Physics, Department of Physics, Chinese Academy of Sciences,University of Science and Technology of ChinaHefei National Laboratory, University of Science and Technology of China

【摘要】 Recent advances in van der Waals(vdW) ferroelectrics have sparked the development of related heterostructures with non-volatile and field-tunable functionalities. In vdW ferroelectric heterojunctions, the interfacial electrical characteristics play a crucial role in determining their performance and functionality. In this study,we explore the interfacial polarization coupling in two-dimensional(2D) ferroelectric heterojunctions by fabricating a graphene/h-BN/CuInP2S6/α-In2Se3/Au ferroelectric field-effect transistor. By varying the gate electric field, the CuInP2S6/α-In2Se3 heterojunction displays distinct interfacial polarization coupling states, resulting in significantly different electrical transport behaviors. Under strong gate electric fields, the migration of Cu ions further enhances the interfacial polarization effect, enabling continuous tuning of both the polarization state and carrier concentration in α-In2Se3. Our findings offer valuable insights for the development of novel multifunctional devices based on 2D ferroelectric materials.

【Abstract】 Recent advances in van der Waals(vdW) ferroelectrics have sparked the development of related heterostructures with non-volatile and field-tunable functionalities. In vdW ferroelectric heterojunctions, the interfacial electrical characteristics play a crucial role in determining their performance and functionality. In this study,we explore the interfacial polarization coupling in two-dimensional(2D) ferroelectric heterojunctions by fabricating a graphene/h-BN/CuInP2S6/α-In2Se3/Au ferroelectric field-effect transistor. By varying the gate electric field, the CuInP2S6/α-In2Se3 heterojunction displays distinct interfacial polarization coupling states, resulting in significantly different electrical transport behaviors. Under strong gate electric fields, the migration of Cu ions further enhances the interfacial polarization effect, enabling continuous tuning of both the polarization state and carrier concentration in α-In2Se3. Our findings offer valuable insights for the development of novel multifunctional devices based on 2D ferroelectric materials.

【基金】 supported by the Chinese Academy of Sciences Project for Young Scientists in Basic Research (Grant No. YSBR-049);the Innovation Program for Quantum Science and Technology (Grant No. 2021ZD0302800);the Fundamental Research Funds for the Central Universities (Grant No. WK3510000013)
  • 【文献出处】 Chinese Physics Letters ,中国物理快报(英文版) , 编辑部邮箱 ,2025年05期
  • 【分类号】O469
  • 【下载频次】1
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