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兼具高电致应变和居里温度的La掺杂Pb基压电陶瓷的制备
Preparation of La-doped lead-based piezoelectric ceramics with both high electrical strain and Curie temperature
【摘要】 采用传统固相法制备了La3+掺杂的0.28Pb(In1/2Nb1/2)O3-0.32Pb(Zn1/3Nb2/3)O3-0.3PbTiO3-0.1PbZrO3(PIN-PZN-PZT)四元压电陶瓷,研究了La3+掺杂量对PIN-PZN-PZT四元压电陶瓷微观结构和电学性能的影响。结果表明:引入La3+可以增强压电陶瓷局部结构异质性,进而提升介电弛豫特性并提高压电性能。当La2O3含量为1.5%时,获得了兼具高电致应变(0.23%)和高居里温度(206℃)的压电陶瓷材料。
【Abstract】 La3+-doped 0.28Pb(In1/2Nb1/2)O3-0.32Pb(Zn1/3Nb2/3)O3-0.3PbTiO3-0.1PbZrO3(PIN-PZN-PZT) quaternary piezoelectric ceramics were prepared by the conventional solid-phase method,and the effects of La3+ doping on the microstructures and electrical performances of PIN-PZN-PZT quaternary piezoelectric ceramics were investigated.The results show that introducing La3+ can enhance the local structural heterogeneity of piezoelectric ceramics,enhancing the dielectric relaxation properties to improve the piezoelectric performance.When the La2O3 content was 1.5%,piezoelectric ceramic materials with high electrically induced strain (0.23%) and high Curie temperature (206℃) were obtained.
【Key words】 0.28Pb(In1/2Nb1/2)O3-0.32Pb(Zn1/3Nb2/3)O3-0.3PbTiO3-0.1PbZrO3; piezoelectric ceramic; electrical strain; Curie temperature;
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2025年02期
- 【分类号】TQ174.6
- 【下载频次】53