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兼具高电致应变和居里温度的La掺杂Pb基压电陶瓷的制备

Preparation of La-doped lead-based piezoelectric ceramics with both high electrical strain and Curie temperature

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【作者】 卢铭鑫周黎阳许晓宇冯晓颖王挥阎彬许杰陈超梅辉高峰

【Author】 LU Mingxin;ZHOU Liyang;XU Xiaoyu;FENG Xiaoying;WANG Hui;YAN Bin;XU Jie;CHEN Chao;MEI Hui;GAO Feng;State Key Laboratory of Solidification Processing, School of Materials Science and Engineering,Northwestern Polytechnical University;No.771 Institute, No.9 Academy, China Aerospace Science and Technology Corporation;

【通讯作者】 高峰;

【机构】 西北工业大学材料学院,凝固技术国家重点实验室中国航天科技集团有限公司第九研究院第七七一研究所

【摘要】 采用传统固相法制备了La3+掺杂的0.28Pb(In1/2Nb1/2)O3-0.32Pb(Zn1/3Nb2/3)O3-0.3PbTiO3-0.1PbZrO3(PIN-PZN-PZT)四元压电陶瓷,研究了La3+掺杂量对PIN-PZN-PZT四元压电陶瓷微观结构和电学性能的影响。结果表明:引入La3+可以增强压电陶瓷局部结构异质性,进而提升介电弛豫特性并提高压电性能。当La2O3含量为1.5%时,获得了兼具高电致应变(0.23%)和高居里温度(206℃)的压电陶瓷材料。

【Abstract】 La3+-doped 0.28Pb(In1/2Nb1/2)O3-0.32Pb(Zn1/3Nb2/3)O3-0.3PbTiO3-0.1PbZrO3(PIN-PZN-PZT) quaternary piezoelectric ceramics were prepared by the conventional solid-phase method,and the effects of La3+ doping on the microstructures and electrical performances of PIN-PZN-PZT quaternary piezoelectric ceramics were investigated.The results show that introducing La3+ can enhance the local structural heterogeneity of piezoelectric ceramics,enhancing the dielectric relaxation properties to improve the piezoelectric performance.When the La2O3 content was 1.5%,piezoelectric ceramic materials with high electrically induced strain (0.23%) and high Curie temperature (206℃) were obtained.

【基金】 国家自然科学基金(No.52272123)资助
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2025年02期
  • 【分类号】TQ174.6
  • 【下载频次】53
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