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LaFeO3多孔空心球纳米材料的合成及含磷废水处理

Synthesis of LaFeO3 porous hollow sphere nanomaterials and treatment of phosphorus-containing wastewater

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【作者】 MUHAMMAD Yasir; 吕仁江; 刘志何; 宋铭慧; 陈航;

【Author】 MUHAMMAD Yasir;LV Ren-jiang;LIU Zhi-he;SONG Ming-hui;CHEN Hang;College of Chemistry and Chemical Engineering, Qiqihar University;

【通讯作者】 吕仁江;

【机构】 齐齐哈尔大学化学与化学工程学院;

【摘要】 以硝酸镧和葡萄糖酸亚铁为金属源,乙二胺为结构导向剂,尿素为沉淀剂,水为溶剂,采用水热法成功合成LaFeO3多孔空心球纳米结构材料。通过SEM、EDS、TEM、XRD、N2吸附-脱附和XPS测试对合成样品的表面形貌、元素组成和晶体结构进行表征。结果表明,制备的LaFeO3样品具有球形空心结构,直径范围为1~3μm。LaFeO3的比表面积为16.884 m2/g,孔径约为22 nm。探讨La Fe O3纳米材料在水污染环境修复中的应用,特别是磷离子。当吸附剂用量为1.0 g/L,磷酸盐溶液浓度为10 mg/L,磷酸盐去除效率最佳,去除效率为91.17%。

【Abstract】 LaFeO3 porous hollow sphere nanostructure materials were successfully synthesized by hydrothermal method, lanthanum nitrate and ferrous gluconate acted as metal source, ethylenediamine as a structure directing agent, carbamide as precipitant, and water as solvent. The characterization methods that used include SEM, EDS, TEM, XRD, nitrogen adsorption-desorption analysis and XPS. These results show that the obtained LaFeO3 have sphere shape, hollow structure, the diameter of 1-3 μm. Moreover, LaFeO3 possess specific surface area(16.884 m2/g) and porous size distribution(22 nm). This study explores the use of LaFeO3 nanostructure materials, for environmental remediation of water pollution, specifically phosphorus ion. The adsorbent dosages of 1.0 g/L, and the phosphate solution with 10 mg/L, the phosphate removal efficiency is best and the removal rate is up to 91.17%.

【基金】 黑龙江省横向课题“阳极氧化铝腔反微应器开发”(220122121004)
  • 【文献出处】 齐齐哈尔大学学报(自然科学版) ,Journal of Qiqihar University(Natural Science Edition) , 编辑部邮箱 ,2025年05期
  • 【分类号】X703;TB383.1;O647.3
  • 【下载频次】104
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