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甲烷蒸汽重整工艺SCST-201/202型催化剂的应用

Application of SCST-201/202 catalyst in methane steam reforming process

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【作者】 苟芸芸; 许云波; 吉旭; 周利;

【Author】 GOU Yun-yun;XU Yun-bo;JI Xu;ZHOU Li;School of Chemical Engineering,Sichuan University;Sichuan Shutai Chemical Technology Co.,Ltd.;

【通讯作者】 周利;

【机构】 四川大学化学工程学院; 四川蜀泰化工科技有限公司;

【摘要】 为研究甲烷蒸汽重整中SCST-201/202型一段炉转化催化剂的催化剂活性,创建一个基于反应动力学的模型来研究验证,以此为基础介绍甲烷蒸汽重整反应中使用的SCST-201/202型催化剂的基本特性、装填压力降,研究了不同水碳比、进口温度、压力对甲烷转化率、产氢率、CO选择性以及反应器压降的影响。结果表明,SCST-201/2 02型催化剂催化活性好、运行阻力低、抗炭能力优良,能较好地适用于甲烷蒸汽重整制氢装置工业化运行。

【Abstract】 The objective of this research was to scrutinize the catalytic efficacy of the SCST-201/202 catalyst in the primary reformer for methane steam reforming.A reaction kinetics-based model was developed and validated to assess the catalyst’s performance.The study delineates the intrinsic properties of the SCST-201/202 catalyst utilized in methane steam reforming,with particular emphasis on the pressure drop across the catalyst bed.The effects of diverse water-to-carbon ratios,inlet temperatures,and pressures on methane conversion rates,hydrogen yield,CO selectivity,and reactor pressure drop were systematically investigated.The results underscore the catalyst’s superior catalytic activity,minimal operational resistance,and robust resistance to carbon formation,indicating its suitability for industrial-scale methane steam reforming processes aimed at hydrogen production.

【基金】 四川省校企合作项目“节能型低压降天然气转化制氢催化剂研究及应用”(2022DYXJXJ01-LH)资助
  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2025年09期
  • 【分类号】TQ426;TQ116.2
  • 【下载频次】19
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