【摘要】 采用热注入法在相同温度、不同反应时间条件下制备了尺寸均一的CuInSe₂绿色量子点，利用电泳过程沉积到FTO（氟掺杂的二氧化锡）玻璃基底上的TiO₂介孔层中，随后与利用连续离子层沉积法制备的钝化层共同组成ZnS/CuInSe₂/TiO₂复合光阳极。XRD和TEM分析结果表明，成功合成尺寸约8nm的CuInSe₂量子点。对光阳极的光电化学性能进行分析，结果表明，当反应时间为10min、ZnS的沉积层数为4时，光阳极的电流密度最大，为5.27mA·cm^-2，外加偏压光-电转化效率（ABPE）为0.78%，电池的性能最佳。更多还原

【Abstract】 Green CuInSe₂quantum dots with uniform size were prepared by thermal injection method at the same temperature with different reaction time.Through the conjunction of electrophoretically deposited CuInSe₂quantum dots in TiO₂mesoporous layer on a FTO substrate with a passivation ZnS layer prepared by SILAR method,ZnS/CuInSe₂/TiO₂composite photoanode was formed.The results of XRD and TEM proved the successful synthesis of CuInSe₂quantum dots with an average size of approximately 8nm.Based on the analysis of photoelectrochemical performance of photoanodes PEC revealed that the current density of the photoanode reached a maximum of 5.27mA·cm^-2with a reaction time of 10 min and ZnS layer number of 4,while the applied bias photoelectrical conversion efficiency （ABPE）was 0.78%,representing the optimal performance within all cell samples.更多还原