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高黏度缩聚反应器及其研究进展

Research progress on condensation polymerization reactor with high viscosity fluids

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【作者】 成文凯; 颜金钰; 王嘉骏; 冯连芳;

【Author】 CHENG Wenkai;YAN Jinyu;WANG Jiajun;FENG Lianfang;Wuxi Key Laboratory of Efficient and Intelligent Agitated Equipment, Jiangsu Ruiya Stirring Technology Co.Ltd.;State Key Laboratory of Chemical Engineering and Low-Carbon Technology,College of Chemical and Biological Engineering, Zhejiang University;Institute of Zhejiang University-Quzhou;

【通讯作者】 成文凯;

【机构】 江苏瑞亚搅拌科技有限公司无锡市高效智能搅拌装备重点实验室; 浙江大学化学工程与生物工程学院,化学工程与低碳技术全国重点实验室; 浙江大学衢州研究院;

【摘要】 高效缩聚反应器是开发先进聚合工艺的关键。文中综述了几种高黏度缩聚反应器,包括卧式单轴反应器、卧式双轴反应器、立式降膜式反应器和立式组合式反应器,进一步阐述了缩聚反应器设备特性及其应用研究进展,并指出成膜性能和表面更新性能是强化传质过程的关键。此外,计算流体力学(CFD)模拟是研究设备特性的主要方法,将不同结构成膜元件进行有效组合可以开发新型反应器,将不同性能反应器组合可以制备高性能、高分子量聚合物,优化聚合工艺以及开发先进的聚合工艺。研究可为高效缩聚反应器的开发提供思路。

【Abstract】 The highly efficient condensation polymerization reactor is the key to develop advanced polymerization process. This article reviews several types of highly viscous condensation polymerization reactor, including horizontal single-shaft reactors, horizontal twin-shaft reactors, vertical falling film reactors and vertical combined reactors. Research progress on equipment characteristics and application of condensation polymerization reactors was also reported. It is pointed out that the film formation and surface renewal performance are key factors to enhance mass transfer process. Computational fluid dynamics(CFD) simulation is the main method for studying equipment characteristics. Effective combination of different film forming elements can be used to develop novel reactors.Combination of reactors with different performance can be used to prepare polymers with high performance and high molecular weight, optimize polymerization processes, and to develop advanced polymerization processes. The study can provide ideas for the development of highly efficient condensation polymerization reactor.

【基金】 国家自然科学基金(22078284);宜兴市“陶都英才”科技创新人才项目(CX202314)
  • 【文献出处】 高校化学工程学报 ,Journal of Chemical Engineering of Chinese Universities , 编辑部邮箱 ,2025年05期
  • 【分类号】TQ315
  • 【下载频次】13
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