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中高温“硬核-强界面”的高强韧耐磨钛合金制备与研究

Preparation and Study of High-Strength and Wear-Resistant Titanium Alloys with “Hard Core-Strong Interface” at Moderate Temperature

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【作者】 李娟刘畅王璐李洞亭周立玉刘颖

【Author】 Li Juan;Liu Chang;Wang Lu;Li Dongting;Zhou Liyu;Liu Ying;College of Materials Science and Engineering,Sichuan University;

【通讯作者】 刘颖;

【机构】 四川大学材料科学与工程学院

【摘要】 为改善钛(Ti)的硬度和耐磨性,通过在纯钛(Ti)中引入TiB2硬质相,基于放电等离子烧结(SPS)技术控制二者的反应进程,在Ti基体中构建出继承B元素扩散路径的TiB2-TiB-Ti“硬核-强界面”组织结构。最终在TiB2添加量40%时,获得了室温下863.5 HV5以及400℃下720.9 HV5的高硬度,其在相同摩擦条件下,室温至400℃温域内的摩擦性能皆优于商用TC4高温钛合金。与此同时,得益于优良的结合界面,该合金还展示出独特的高温高强韧特性,在400℃下仍保持了1120 MPa的高抗压强度与约11.7%的应变。本研究设计思路具有启发与普适性,有望为新型中高温高强韧耐磨钛合金材料的研发提供新方法,推动相关材料在航空航天领域的应用。

【Abstract】 To improve the hardness and wear resistance of titanium(Ti), it is proposed to introduce TiB2 hard phase into pure Ti to accurately control the reaction process of the two components based on the discharge plasma sintering(SPS) technique, and to construct a TiB2-TiB-Ti “hardcore-strong-interface” structure in Ti matrix that inherits the diffusion path of B element. Finally, a high hardness of 863.5 HV5 at room temperature and 720.9 HV5 at 400 ℃ is obtained with the addition of 40% TiB2, which makes its friction performance better than that of commercial TC4 high-temperature titanium alloys under the same friction conditions in the temperature range from room temperature to 400 ℃.At the same time, thanks to its excellent bonding interface, the alloy also exhibits unique high-temperature and high-toughness properties,maintaining a high compressive strength of 1120 MPa and strain of about 11.7% at 400 ℃. The design idea of this study is inspiring and universal,which is expected to provide a new method for the research and development of new medium-high-temperature and high-toughness wear-resistant titanium alloys, and to promote the application of related materials in aerospace field.

【基金】 四川省重点研发计划(2023ZDZX0028)
  • 【文献出处】 稀有金属材料与工程 ,Rare Metal Materials and Engineering , 编辑部邮箱 ,2025年07期
  • 【分类号】TG146.23
  • 【下载频次】23
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