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化学浴法制备硒硫化锑薄膜及其相应太阳电池光伏性能的研究

Chemical Bath Deposition of Antimony Selenosulfide Thin Films and the Photovoltaic Performance of the Corresponding Solar Cells

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【作者】 陈文进史成武

【Author】 Chen Wenjin;Shi Chengwu;School of Chemistry and Chemical Engineering, Hefei University of Technology;

【通讯作者】 史成武;

【机构】 合肥工业大学化学与化工学院

【摘要】 利用酒石酸锑钾、硫代硫酸钠、硒代硫酸钠作为锑、硫、硒源,通过化学浴法成功制备了硒硫化锑(Sb2S3-ySey)薄膜,组装了结构为FTO/CdS/Sb2S3-ySey/spiro-OMeTAD/Au的太阳电池,系统研究了化学浴生长时间对所得Sb2S3-ySey薄膜的微结构、晶相、光学吸收及其相应太阳电池光伏性能的影响。结果表明,当生长时间为5h、7h、9h时,所得Sb2S3-ySey薄膜的厚度为70nm、100nm、110nm,相应太阳电池的光电转换效率为5.27%、5.66%、5.64%。

【Abstract】 Antimony selenosulfide(Sb2S3-ySey) thin films were successfully prepared by chemical bath deposition(CBD) using antimony potassium tartrate, sodium thiosulfate and sodium selenosulfate as sources of antimony, sulfur and selenium. The solar cells with the architecture of FTO/CdS/Sb2S3-ySey/spiro-OMeTAD/Au were fabricated. The influence of CBD growth time on the microstructure, crystalline phase, optical absorption of Sb2S3-ySey thin films and the photovoltaic performance of the corresponding solar cells was systematically investigated. When the growth time of CBD was 5 h, 7 h,9 h, the thickness of Sb2S3-ySey thin films was 70 nm, 100 nm, 110 nm, and the power conversion efficiency of the corresponding solar cells was 5.27%,5.66%, 5.64%.

【基金】 国家自然科学基金项目“全固态铅基硫族化合物薄膜敏化TiO2纳米棒阵列太阳电池的制备与光伏性能关系的研究”(项目编号:51972091)
  • 【文献出处】 当代化工研究 ,Modern Chemical Research , 编辑部邮箱 ,2024年01期
  • 【分类号】TB383.2;TM914.4
  • 【下载频次】2
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