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化学机械浆制浆原料中过渡金属离子对其漂白性能的影响

Effects of Transition Metal Ions in Raw Materials on the Bleachability of Chemical Mechanical Pulps

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【作者】 焦婷赵志坤朱北平焦健房桂干邓拥军张凤山

【Author】 JIAO Ting;ZHAO Zhikun;ZHU Beiping;JIAO Jian;FANG Guigan;DENG Yongjun;ZHANG Fengshan;Jiangsu Key Lab of Biomass Energy and Material,Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources,Key Lab of Chemical Engineering of Forest Products,National Forestry and Grassland Administration,National Engineering Research Center of Low-Carbon Processing and Utilization of Forest Biomass,Institute of Chemical Industry of Forestry Products,CAF;Yunnan Yunjing Forestry and Paper Industry Co.,Ltd.;Shandong Huatai Paper Co.,Ltd.;

【通讯作者】 焦健;房桂干;

【机构】 中国林业科学研究院林产化学工业研究所,江苏省生物质能源与材料重点实验室,江苏省林业资源高效加工利用协同创新中心,国家林业和草原局林产化学工程重点实验室,林木生物质低碳高效利用国家工程研究中心云南云景林纸股份有限公司山东华泰纸业股份有限公司

【摘要】 本研究以我国化学机械浆生产中主要使用的3种桉木和3种杨木为研究对象,比较了其浆料和预浸渍溶出物中过渡金属离子含量的差异,分析了过渡金属离子含量对浆料漂白性能以及预浸渍溶出物抗氧化性的影响。结果表明,桉木原料中较多的Mn2+和杨木中较多的Fe3+导致浆料的漂白性能较差;桉木和杨木预浸渍溶出物中较多的Fe3+导致二者的抗氧化性较强,由此导致实际生产中化学品消耗量较高;对于完全脱除预浸渍溶出物的浆料,增加螯合剂用量对杨木的漂白性能无显著影响,对桉木的漂白性能有一定提高;对于保留预浸渍溶出物浆料,增加螯合剂用量比增加H2O2用量对2种浆料漂白性能的改善作用更明显。

【Abstract】 In this study, three kinds of eucalyptus woods and three kinds of poplar woods, which were mainly used in the production of chemical mechanical pulp, were compared with the difference of transition metal ion content in the pulp and the pre-impregnated residues. The effects of transition metal ions in the pulp on the bleachability and the effects of metal ions in the pre-impregnated residues on oxidation resistance were analyzed. The results showed that high contents of Mn2+ in eucalyptus and the high contents of Fe3+ in poplar resulted in poor bleachability of the pulp. The high contents of Fe3+ in eucalyptus and poplar pre-impregnated residues led to the strong antioxidant properties, which resulted in high chemical consumption in actual production. For the completely removal of pre-impregnated residues, increasing the dosage of chelating agent had no significant effect on the bleachability of poplar, but had certain improvement on the bleachability of eucalyptus. For fully retained pre-impregnated residues, increasing the dosage of chelating agent had more obvious improvement on the bleachability than increasing the dosage of hydrogen peroxide.

【基金】 国家自然科学基金面上项目“竹材机械浆中顽固发色基团的结构特点及其脱除机理研究”(32271974);泰山产业领军人才工程专项经费(tscy20200213)
  • 【文献出处】 中国造纸 ,China Pulp & Paper , 编辑部邮箱 ,2024年12期
  • 【分类号】TS745
  • 【下载频次】16
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