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溶剂依赖型碳点的制备及水含量检测和防伪应用

Preparation of Solvent-Dependent Carbon Dots for Water Content Detection and Anti-Counterfeiting

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【作者】 崔赛孟雅婷王松柏董川双少敏

【Author】 CUI Sai;MENG Ya-Ting;WANG Song-Bai;DONG Chuan;SHUANG Shao-Min;School of Chemistry and Chemical Engineering,and Institute of Environmental Science,Shanxi University;School of Public Health,Shanxi Key Laboratory of Environmental Health Impairment and Prevention,MOE Key Laboratory of Coal Environmental Pathogenicity and Prevention,Shanxi Medical University;

【通讯作者】 双少敏;

【机构】 山西大学化学化工学院,环境科学研究所山西医科大学公共卫生学院,环境健康损害山西省重点实验室,煤炭环境致病与防治教育部重点实验室

【摘要】 以二苯氨基-4-苯甲醛和邻苯二胺为前驱体,乙醇为溶剂,采用溶剂热法合成了具有高量子产率(QY=87.76%)的氮掺杂荧光碳点(N-CDs)。通过对有机溶剂和水溶液中N-CDs光学性质的考察,表明N-CDs具有良好的溶剂依赖性和化学稳定性。水的加入在N-CDs中构建氢键网格,从而实现了发射波长的红移,N-CDs溶液由蓝色变为黄色。进一步,基于N-CDs荧光试纸蓝色到黄色的可逆颜色变化,制备便携的空气湿度可视化检测试纸。此外,N-CDs还可用于荧光墨水、书写纸和荧光柔性薄膜,拓展了其在信息传递,高级防伪加密和固态荧光的应用。

【Abstract】 Nitrogen doped fluorescent carbon dots(N-CDs) with high quantum yield(QY=87. 76%) were synthesized by solvothermal method using diphenylamino-4-benzaldehyde and o-phenylenediamine as raw materials and ethanol as solvent. The optical properties of N-CDs in organic solvents and aqueous solutions were investigated, indicating that N-CDs have good solvent dependence and chemical stability. The addition of water constructed a hydrogen bonding grid in N-CDs, thereby achieving a redshift in emission wavelength, and the N-CDs solution changes from blue to yellow. Furthermore, based on the reversible color change from blue to yellow of N-CDs fluorescent test strips, a portable air humidity visualization detection test strip was prepared. In addition, N-CDs can also be used for fluorescent ink, writing paper, and fluorescent flexible films, which expanding their applications in information transmission, advanced anti-counterfeiting encryption, and solid-state fluorescence.

【基金】 国家自然科学基金(No.22274090);山西省回国留学人员科研项目(No.2021-011)资助~~
  • 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2024年07期
  • 【分类号】O657.3;TB383.1
  • 【下载频次】21
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