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纤维素纳米纤维/石墨烯基超疏水电磁屏蔽纺织品的制备

Preparation of superhydrophobic and electromagnetic shielding textiles based on cellulose nanofibers/graphene

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【作者】 彭宇斐徐丽慧蔡央芳夏雯蕙施绪伦罗畅沈天女王黎明

【Author】 PENG Yufei;XU Lihui;CAI Yangfang;XIA Wenhui;SHI Xulun;LUO Chang;SHEN Tiannü;WANG Liming;School of Textiles and Fashion, Shanghai University of Engineering Science;

【通讯作者】 徐丽慧;

【机构】 上海工程技术大学纺织服装学院

【摘要】 以氧化石墨烯(GO)与纤维素纳米纤维(CNF)为原料,制备了纤维素纳米纤维/还原氧化石墨烯(CNF@RGO)复合材料,并将其与聚二甲基硅氧烷(PDMS)结合整理到棉织物表面,制备了超疏水电磁屏蔽纺织品。采用扫描电子显微镜(SEM)、傅里叶红外光谱(FTIR)等对复合材料及整理织物的表面形貌和结构进行表征。结果表明,基于CNF@RGO复合材料在整理棉织物表面构建了微观粗糙结构,PDMS将CNF@RGO复合材料牢牢包覆在棉纤维表面,同时降低了整理织物的表面能。整理棉织物在频率为8.368GHz时最小反射损耗为-23.6 dB,表面水滴接触角可达153.7°,实现了优异的电磁屏蔽性、防污及自清洁性能。

【Abstract】 Cellulose nanofiber/reduced-oxide graphene(CNF@RGO) composites were prepared using graphene oxide(GO) and cellulose nanofiber(CNF). CNF@RGO composites and poly-dimethylsiloxane(PDMS)were used to coat cotton fabrics to prepare superhydrophobic and electromagnetic shielding textiles. The surface morphology and structure of CNF@RGO composites and coated fabrics were characterized by scanning electron microscope(SEM) and fourier-transform infrared spectrometry(FTIR). The results showed that the treated cotton fabric had surface roughness based on the microscopic rough structure of CNF@RGO composites. The CNF@RGO composites were firmly coated on the surface of the coated cotton fiber with the help of PDMS. PDMS reduced surface energy of the treated cotton fabric. The treated cotton fabric showed minimum reflective loss of-23.6 dB at a frequency of 8.368 GHz and water droplet contact angle of 153.7°, achieving excellent electromagnetic shielding, anti-fouling and self-cleaning properties.

【基金】 国家自然科学基金项目(51703123);国家先进印染技术创新中心科研基金项目(2022GCJJ22);上海市自然科学基金项目面上项目(21ZR1426200);上海市级大学生创新训练项目(CS2209009)
  • 【文献出处】 印染助剂 ,Textile Auxiliaries , 编辑部邮箱 ,2024年02期
  • 【分类号】TS195.5
  • 【下载频次】78
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