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松辽盆地砂岩型铀矿铀含量配分比例的半定量分析

Semi-Quantitative Analysis of Uranium Content Distribution Ratio in a Sandstone-Type Uranium Deposit in Songliao Basin

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【作者】 刘明义吴柏林杨松林郝欣王苗李琪林周洋张效瑞

【Author】 LIU Mingyi;WU Bailin;YANG Songlin;HAO Xin;WANG Miao;LI Qi;LIN Zhouyang;ZHANG Xiaorui;State Key Laboratory of Continental Dynamics;Department of Geology,Northwest University;Xi’an Center,China Geological Survey;The Exploration and Development Research Institute of Liaohe Oilfield Branch Company,PetroChina;

【通讯作者】 吴柏林;

【机构】 大陆动力学国家重点实验室,西北大学地质学系中国地质调查局西安地质调查中心中国石油辽河油田分公司勘探开发研究院

【摘要】 钱家店铀矿是位于松辽盆地南部的复成因砂岩型铀矿,受表生淋滤、辉绿岩中低温热液和深部油气等多流体影响,目前铀矿物赋存状态尚有一定争议,铀在矿石内不同矿物中的配分尚不明确。为了进一步明确铀赋存状态和在不同矿物中的配分,计算钱家店矿石中不同矿物中铀的配分比例,本文运用岩矿鉴定、铀化学逐级提取、电子探针和激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)微区原位分析技术开展综合测试分析。明确了钱家店铀矿物的赋存状态,认为钱家店铀矿物以吸附态为主,约占总铀含量的80%,结合态铀矿物或含铀矿物约占比20%。其中吸附态铀矿物主要富集在方解石等碳酸盐矿物中,占总铀含量的47.86%,其次是在黏土矿物中占17.94%,在铁锰氧化物矿物中占12.21%。独立铀矿物是与黄铁矿密切共生的沥青铀矿为主,约占铀总含量的9.07%,另有少量含钛铀矿物和铀石约占5.08%。这种矿石中各碎屑组分中铀的占比量化研究,为矿床地浸开采及资源量计算提供依据。

【Abstract】 The Qianjiadian uranium deposit is a complex-metamorphic sandstone-type uranium mine located in the southern part of the Songliao Basin. To determine the state of uranium mineralization and its partitioning in different minerals, petrographic identification, uranium chemical step-by-step extraction, electron probe microanalysis and laser ablation inductively coupled plasma-mass spectrometry(LA-ICP-MS) were used. The results show that Qianjiadian uranium minerals are predominantly in adsorbed state, accounting for about 80% of the total uranium content, of which 47.86% is in carbonate minerals, such as calcite, 17.94% in clay minerals, and 12.21% in iron and manganese oxides minerals. Combined or uranium-bearing minerals account for approximately20% of the total uranium content, of which stand-alone uranium minerals are dominated by pitchblende uranium ore, which accounts for approximately 9.07% of the total uranium content, and a small amount of titanium-bearing uranium minerals and uraninite, which accounts for approximately 5.08%.

【基金】 国家重点研发计划项目(2023YFC2906702,2021YFE0190500,2021YFC2901802);中国地质调查局地质调查项目(DD20230582);中核铀业“揭榜挂帅”科技攻关项目(202302)
  • 【文献出处】 岩矿测试 ,Rock and Mineral Analysis , 编辑部邮箱 ,2024年02期
  • 【分类号】P619.14
  • 【下载频次】25
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