节点文献

基于二苯甲酮季铵盐化合物改善PA6的抗紫外性能

Improving UV resistance of PA6 based on benzophenone quaternary ammonium compound

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 蒋永金龚静华马敬红

【Author】 JIANG Yongjin;GONG Jinghua;MA Jinghong;State Key Laboratory of Fiber Material Modification, School of Materials Science and Engineering, Donghua University;

【通讯作者】 马敬红;

【机构】 东华大学材料科学与工程学院,纤维材料改性国家重点实验室

【摘要】 以2, 4-二羟基-二苯甲酮、二甲氨基氯乙烷盐酸盐和溴代烷为原料,采用二步法制备了二苯甲酮季铵盐化合物(BP-Qas)。将BP-Qas引入聚己内酰胺(PA6)中,以溶液流延方式制备抗紫外PA6薄膜。其紫外光谱结果表明,当BP-Qas质量分数为1.5%时,抗紫外膜在200~350 nm实现了对紫外光线的零透过、零反射。同时,采用BP-Qas对PA6织物进行后整理,当pH=4、BP-Qas质量分数为3%时,PA6织物具有良好的抗紫外效果,其紫外线防护系数(UPF)达到50+。

【Abstract】 Quaternary ammonium benzophenone compounds(BP-Qas) is prepared by two-step method, using2,4-dihydroxy-benzophenone, dimethylaminochloroethane hydrochloride and bromooctane as raw materials.BP-Qas is introduced into polycaprolactam(PA6) and the anti-ultraviolet PA6 film is prepared by solution casting. The ultraviolet spectrum results show that when the concentration of BP-Qas is 1.5%, the anti-ultraviolet film achieves zero transmission and zero reflection of ultraviolet light at 200-350 nm. At the same time, BPQas is used to the finish of PA6 fabric. When p H is 4 and the concentration of BP-Qas is 3%, PA6 fabric has a good anti-ultraviolet effect, and its ultraviolet protection factor(UPF) reaches 50+.

  • 【文献出处】 印染 ,China Dyeing & Finishing , 编辑部邮箱 ,2024年06期
  • 【分类号】TS195.5
  • 【下载频次】65
节点文献中: 

本文链接的文献网络图示:

本文的引文网络