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偶联剂对磁性丁腈橡胶磁性能的影响

Effect of Coupling Agents on Magnetic Properties of Magnetic NBR

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【作者】 刘旭梁琳刘奕麟丁乃秀张保岗

【Author】 LIU Xu;LIANG Lin;LIU Yilin;DING Naixiu;ZHANG Baogang;Sinochem International Oil(Tianjin) Co.,Ltd;Qingdao University of Science and Technology;

【通讯作者】 张保岗;

【机构】 中化国际石油(天津)有限公司青岛科技大学高性能聚合物及成型技术教育部工程研究中心

【摘要】 分别选用2种硅烷偶联剂和4种钛酸酯偶联剂制备磁性丁腈橡胶(NBR),研究偶联剂对磁性NBR磁性能的影响。结果表明:添加钛酸酯偶联剂的胶料的磁性能优于添加硅烷偶联剂的胶料,其中添加钛酸酯偶联剂A13的胶料的磁性能最优;随着偶联剂用量的增大,胶料的剩磁(Br)、内禀矫顽力(HCJ)和最大磁能积[(BH)max]先增大后减小,矫顽力(HCB)无明显变化规律;当钛酸酯偶联剂A13用量为磁粉用量的1%时,胶料具有最优的磁性能:Br 0.224 T,HCB 165kA·m-1,HCJ 279 kA·m-1,(BH)max 9.7 kJ·m-3

【Abstract】 In this paper,two kinds of silane coupling agents and four kinds of titanate coupling agents were used to prepare magnetic nitrile rubber(NBR),and the influence of coupling agents on the magnetic properties of magnetic NBR was investigated.The results showed that the magnetic properties of the compounds with titanate coupling agents were better than those with silane coupling agents,among which the magnetic properties of the compound added with titanate coupling agent A13 were the best.With the increase of the dosage of coupling agent A13,remanence(Br),intrinsic coercivity(HCJ) and maximum magnetic energy product(BH)max increased first and then decreased,while coercivity(HCB) had no obvious change pattern.When the dosage of coupling agent A13 was 1% of the dosage of magnetic powder,the compound had the optimal magnetic properties:Br 0.224 T,HCB 165 kA·m-1,HCJ 279 kA·m-1,(BH)max 9.7 kJ·m-3.

【关键词】 偶联剂磁性丁腈橡胶磁性能
【Key words】 coupling agentmagnetic NBRmagnetic property
【基金】 国家自然科学基金资助项目(51972185)
  • 【文献出处】 橡胶工业 ,China Rubber Industry , 编辑部邮箱 ,2024年04期
  • 【分类号】TQ333.7
  • 【下载频次】49
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