【摘要】 以铜片作为阳极,底部带有小孔的石英管中插入的铜片作为阴极,在多壁碳纳米管（MWCNTs）和Na Cl水溶液中通过隔膜辉光放电（DGD）等离子体技术一步合成了Cu₂O/Cu O/MWCNTs纳米复合材料,并对其传感葡萄糖的性能进行了评价.XRD,XPS和SEM分析表明,Cu₂O/Cu O成功负载于MWCNTs表面.电化学测试发现,Cu₂O/Cu O/MWCNTs纳米材料对葡萄糖的灵敏度为1857,检出限为0.09μmol·L^-1（n=11）,对实际样品5%葡萄糖注射液的测定值和标签值一致,回收率为97%～110%.以上结果表明,隔膜辉光放电技术是一种制备Cu₂O/Cu O/MWCNTs纳米材料的绿色、环保新技术,制备的材料可用于葡萄糖的高灵敏检测.更多还原

【Abstract】 Cu₂O/CuO/MWCNTs nanocomposites were synthesized by diaphragm glow discharge（DGD） plasma in carbon nanotubes（MWCNTs） and NaC l solution using copper plate as anode and copperp late insert ed into a quartz tube with smallholes at the bottom as cathode.The glucose sensi ngpropertiesof Cu₂O/CuO/MWCNTs were evaluated.XRD,XPS and SEM analysis showed thatCu₂O/CuO i s successfully loaded on the surface of MWCNTs.The electrochemical testi ndicated the sensitivity of Cu₂O/CuO/MWCNTs nanomaterials to glucose is 1 857,and the detection limit is 0.09μmol·L^-1（n=11）.The measured value of 5% glucose injection in real samples is consistent with the lab el va lue,and the recovery rate is 97%～110%.The above results show that the DGDtechnologyis agree n and environmentally friendly technique for preparing Cu₂O/CuO/MWCNTs nanomaterials,andthe prepared materials can be used for highly sensitive detection of glucose.更多还原