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银铜侧向复合材料界面结合机理分析
Analysis of Interface Bonding Mechanism of Silver-Copper Lateral Composite Prepared by Coated Ingot
【摘要】 本文采用“包覆锭坯+扩散烧结+冷轧复合”联合工艺制备了银铜侧向复合带材,利用金相显微镜(OM)、扫描电镜(SEM)和能谱仪(EDS)观察分析银铜复合界面结构和元素分布,并分析其银铜复合界面的结合机理。结果表明,银铜复合界面形成过程为:1)银铜接触界面处凹凸不平的表面在轧制力的作用下相互咬合,形成机械结合界面;2)接触面在轧制力的作用下,银铜表面氧化膜破裂,新鲜表面质点间在轧制变形热的作用下产生原子结合;3)在扩散烧结过程中,银铜界面处的原子在高温作用下被激活,银铜原子相互扩散,在界面处发生银铜共晶反应形成液相金属层,随着烧结时间的延长,其共晶反应液相层厚度逐渐增加,随后冷凝结晶,使银铜实现侧向冶金结合。4)在后续中间退火过程中,共晶层与两侧的铜、银基体相互扩散,铜、银原子向更深的方向逐渐扩散,在靠近共晶层铜侧和银侧逐步形成固溶体层,使银与铜的结合强度进一步提高。银铜侧向复合界面结合机理包含机械咬合结合、接触共晶反应自钎焊结合和原子扩散结合3种,复合界面结合强度较好,剪切强度达220 MPa。
【Abstract】 In this paper, silver-copper lateral composite strip was prepared by the process of "coated ingot billet diffusion sintering and cold rolling composite". The interfacial bonding strength of silver-copper composite strip was tested by material tensile testing machine.The interfacial structure of silver-copper composite strip was observed by metallographic microscope, scanning electron microscope and energy spectrum, and the structure and bonding mechanism of silver-copper composite strip were analyzed. The results show that the forming process of silver-copper composite interface was as follows: 1) Silver and copper contacted each other under the action of rolling force; 2) The uneven surfaces at the silver-copper contact interface bit each other under the action of rolling force, forming a mechanical bonding interface; 3) Under the action of rolling force, the oxide film on the surface of silver-copper was broken, and atomic bonding occurs between fresh surface particles under the action of rolling deformation heat; 4) In the process of diffusion sintering, the atoms at the silver-copper interface were activated under the action of high temperature, and the silver-copper atoms diffused with each other, so that the silver and copper achieved metallurgical bonding at the connecting surface. The bonding mechanism of the silver-copper lateral composite interface included two kinds of bonding mechanisms: mechanical occlusion bonding and atomic diffusion bonding. The bonding strength of the composite interface was good, and the shear strength of the composite interface was 220 MPa.
【Key words】 coated ingot; silver copper composite material; interface bonding mechanism; eutectic contact reaction brazing; microstructure;
- 【文献出处】 铜业工程 ,Copper Engineering , 编辑部邮箱 ,2024年02期
- 【分类号】TB331;TG335.12;TG454
- 【下载频次】41