【摘要】 电催化水分解技术被认为是一种实现可再生能源的重要手段，可以分为阳极析氧反应和阴极析氢反应，而金属-有机框架材料被广泛应用于电催化析氧反应领域。铁作为过渡金属具有独特的电子结构和最大化金属利用率的优点，铁基金属-有机框架材料在电催化水分解反应中表现出良好的应用前景。综述了铁基金属-有机框架材料在电催化水分解中的最新研究进展，并对其衍生材料的制备方法及其微观结构对催化活性、稳定性和析氧能力的影响做了介绍。最后，提出了高性能电催化析氧反应催化剂的设计策略，并对其在电催化析氧领域的应用前景进行了展望。更多还原

【Abstract】 Electrocatalytic water splitting technology is considered to be an important method to achieve renewable energy, which can be divided into anodic oxygen evolution reaction and cathodic hydrogen evolution reaction. Metal-organic frameworks are widely used in the field of electrocatalytic oxygen evolution reaction due to their ultra-high specific surface area and excellent metal active sites. As a transition metal, Fe has the advantages of unique electronic structure and maximizing metal utilization. Therefore, Fe-based metal-organic framework materials show good application prospects in electrocatalytic water splitting reactions. This review summarizes the latest research progress of Fe-based metal-organic framework materials in electrocatalytic water splitting, and introduces the preparation methods and structures of their derivative materials on catalytic activity, stability and oxygen evolution capacity. Finally, the design strategy of high-performance catalyst for electrocatalytic oxygen evolution reaction is proposed, and its application prospect in the field of electrocatalytic oxygen evolution is prospected.更多还原