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费-托合成油加氢裂化催化剂RCF-1的开发与工业应用

DEVELOPMENT AND COMMERCIAL APPLICATION OF HYDROCRACKING CATALYST RCF-1 FOR FISCHER-TROPSCH SYNTHETIC OIL

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【作者】 董松涛李猛王锦业梁家林胡志海吴昊

【Author】 Dong Songtao;Li Meng;Wang Jinye;Liang JiaLin;Hu Zhihai;Wu Hao;SINOPEC Research Institute of Petroleum Processing Co.,Ltd.;

【通讯作者】 董松涛;

【机构】 中石化石油化工科学研究院有限公司

【摘要】 为加工费-托合成油,在优化酸性材料的类型、选择合适的介孔硅铝组分的基础上,开发了费-托合成油加氢裂化催化剂RCF-1,该催化剂具有温度敏感性低和中间馏分油选择性高等特点。工业应用结果表明,以RCF-1催化剂为基础,使用低温法费-托合成油加氢提质CFH~L技术,异构加氢裂化单元生产的柴油馏分十六烷值为76,凝点为-33℃。稳定加氢和异构加氢裂化石脑油馏分适合作为蒸汽裂解料。

【Abstract】 In order to process Fischer-Tropsch(F-T) synthetic oil, on the basis of optimizing the acidic component of the catalyst to improve the temperature sensitivity of the catalyst and selecting the suitable mesoporous silica-aluminum components, catalyst RCF-1 for isomerization-hydrocracking of F-T wax was developed, which had low temperature sensitivity and high selectivity of middle-distillate. Based on this catalyst, the low-temperature F-T hydrotreating and hydrofinishing CFH~L technology was employed. The commercial application of the catalyst RCF-1 showed that the cetane number and freezing point of the diesel distillate produced by the isomerization-hydrocracking unit were 76 and-33 ℃,respectively, using the low-temperature process for the hydrogenation of F-T synthetic CFH~L. The stabilization-hydrogenation and isomerization-hydrocracking naphtha fractions are particularly suitable as steam cracking feed.

【基金】 国家重点研发计划项目(2021YFA1501204)
  • 【文献出处】 石油炼制与化工 ,Petroleum Processing and Petrochemicals , 编辑部邮箱 ,2024年05期
  • 【分类号】TE624.93
  • 【下载频次】4
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