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聚丙烯/聚二甲基硅氧烷防尘复合材料的制备及性能

Preparation and Properties of Polypropylene/Polydimethylsiloxane Dustproof Composites

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【作者】 周尧姜凤阳车秋凌思芳周亮刘松涛王俊勃

【Author】 ZHOU Yao;JIANG Feng-yang;CHE Qiu-ling;SI Fang;ZHOU Liang;LIU Song-tao;WANG Jun-bo;College of Materials Engineering,Xi’an University of Engineering;Anta (China) Co.,Ltd.;Shaanxi Dingxin Huizhi Functional Materials Technology Co.,Ltd.;

【通讯作者】 姜凤阳;

【机构】 西安工程大学材料工程学院安踏(中国)有限公司陕西鼎新汇智功能材料科技有限公司

【摘要】 为提升聚合物防尘性能,以聚丙烯(PP)为基体,聚二甲基硅氧烷(PDMS)和内添加型抗静电剂(JN-MN)为填料,通过熔融共混法制备聚丙烯/聚二甲基硅氧烷(PP/PDMS)和聚丙烯/聚二甲基硅氧烷/抗静电剂(PP/PDMS/K)防尘复合材料。采用傅里叶红外分析仪、接触角测试仪、场发射扫描电镜、万能试验机等测试复合材料,探究不同含量PDMS和抗静电剂对复合材料防尘性能、表面电阻率、结晶性能、力学性能的影响。结果表明:随着PDMS含量增加,PP/PDMS复合材料的疏水性能逐渐增强。当PDMS含量为8%时,复合材料的水接触角提升27.7%,其表面能降低7.13%。当抗静电剂含量增加,复合材料的结晶度降低,表面电阻相较于纯PP降低了5个数量级。添加3%抗静电剂已达到饱和,PP/PDMS/K复合材料除尘率提高至88.93%,拉伸强度和弯曲强度下降,但冲击韧性仍保持较高水平。

【Abstract】 In order to improve the dustproof performance of the polymer, polypropylene(PP) was used as the matrix, and polydimethylsiloxane(PDMS) and internally added antistatic agent(JN-MN) were used as fillers to prepare polypropylene/polydimethylsiloxane(PP/PDMS) and polypropylene/polydimethylsiloxane/antistatic agent(PP/PDMS/K) dustproof composites by melt blending. The composite was tested by Fourier infrared analyzer, contact angle tester, field emission scanning electron microscope and universal testing machine. The effects of different content of PDMS and antistatic agents on the dustproof properties, surface resistivity, crystallization properties and mechanical properties of the composites were investigated. The results show that with the increase of PDMS content, the hydrophobic properties of PP/PDMS composites gradually increase. When the PDMS content is 8%, the water contact angle of the composite increases by 27.7%, and the surface energy decreases by 7.13%. When the content of antistatic agent increases, the crystallinity of the composites decreases, and the surface resistivity decreases by 5 orders of magnitude compared with pure PP. Adding 3% antistatic agent has reached saturation, the dust removal rate of PP/PDMS/K composite increases to 88.93%, the tensile strength and bending strength decrease, but the impact toughness still maintains a high level.

【关键词】 聚丙烯聚二甲基硅氧烷抗静电防尘
【Key words】 PolypropylenePolydimethylsiloxaneAntistaticDustproof
【基金】 西安市科技计划项目(2023GXFW0021);中国纺织工业联合会科技指导性计划项目(2021006);泉州市科技计划项目(2023GXFW0021);陕西省技术创新引导计划(2024QCY-KXJ-021);陕西省科技厅三项改革项目(2024ZC-YYDP-17)
  • 【文献出处】 塑料科技 ,Plastics Science and Technology , 编辑部邮箱 ,2024年06期
  • 【分类号】TB332
  • 【下载频次】17
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