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POE链结构对PP/POE共混复合材料结构与性能的影响

Effect of POE Chain Structure on Structure and Properties of PP/POE Blends

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【作者】 李振谢永健马辰宇王平陈明

【Author】 LI Zhen;XIE Yong-jian;MA Chen-yu;WANG Ping;CHEN Ming;School of Chemistry and Chemical Engineering, Hefei University of Technology;Sichuan Changhong Molding Technology Co., Ltd.;Anhui Key Laboratory of Advanced Functional Materials and Devices;School of Materials and Chemical Engineering,Anhui Jianzhu University;

【通讯作者】 陈明;

【机构】 合肥工业大学化学与化工学院四川长虹模塑科技有限公司先进功能材料与器件安徽省重点实验室安徽建筑大学材料与化学工程学院

【摘要】 为探究聚烯烃弹性体(POE)链结构差异对聚丙烯/聚烯烃弹性体(PP/POE)复合材料结构与性能的影响,选取链段结构不同的POE、滑石粉母粒(Talc)与PP进行熔融共混,制备PP/POE复合材料。采用熔体流动速率测试仪、电子万能试验机、悬臂梁冲击试验机、热重分析仪(TG)、差示扫描量热仪(DSC)、场发射扫描电子显微镜(FESEM)对PP复合材料的结构和性能进行表征。结果表明:与乙烯-1-丁烯共聚物(POE-C4)相比,乙烯-1-辛烯共聚物(POE-C8)在保持PP/POE复合材料拉伸强度的同时,提升了复合材料的韧性。POE链结构的差异对PP/POE复合材料的热稳定性能没有明显影响。

【Abstract】 In order to investigate the effect of the polyolefin elastomer(POE) chain structure difference on the structure and properties of polypropylene/polyolefin elastomer(PP/POE) composites, POE with different chain structure, talc masterbatch(Talc) and PP were melt blended to prepare PP/POE composites. The structure and properties of PP composites were characterized by a melt flow rate tester, an electronic universal tester, a cantilever impact tester, a thermogravimetric analyzer(TG), a differential scanning calorimeter(DSC) and a field emission scanning electron microscope(FESEM). The results show that compared with an ethylene-1-butene copolymer(POE-C4), an ethylene-1-octene copolymer(POE-C8) not only maintains the tensile strength of PP/POE composites, but also improves the toughness of the composites. The difference in POE chain structure has no obvious effect on the thermal stability of PP/POE composites.

【基金】 校地合作产业创新引导最近平台项目(JZ2020YDZJ0005)
  • 【文献出处】 塑料科技 ,Plastics Science and Technology , 编辑部邮箱 ,2024年01期
  • 【分类号】TB332
  • 【下载频次】64
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