【摘要】 以含能配体3-氨基吡唑-4-羧酸（H2apza）构筑了一种新型Ni（Ⅱ）基配合物Ni（Hapza）₂（H₂O）₄，利用元素分析、红外光谱、紫外光谱、热重分析等对其进行结构表征。利用差示扫描量热测试和Kissinger方法研究了配合物对高氯酸铵（AP）的催化性能，结果表明，该配合物对AP具有良好的催化作用。更多还原

【Abstract】 A novel Ni（Ⅱ）based complex Ni（Hapza）₂（H₂O）₄was constructed by an energetic ligand 3-aminopyrazole-4-carboxylic acid（H2apza）.Elemental analysis,infrared spectroscopy,ultraviolet spectroscopy and thermogravimetric analysis were used to determine the structure of the complex.The catalytic performance of the complex towards ammonium perchlorate （AP） was studied using differential scanning calorimetry and Kissinger method,which indicate that the complex has a good catalytic effect on AP.更多还原