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草酸离子液体脱除模拟油中的碱性氮化物

REMOVING BASIC NITROGEN FROM SIMULATED OIL USING OXALIC ACID IONIC LIQUID

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【作者】 刘宇新; 朱希平; 关慧敏; 闫锋; 孙方力;

【Author】 Liu Yuxin;Zhu Xiping;Guan Huimin;Yan Feng;Sun Fangli;College of Petrochemical Engineering, Liaoning Petrochemical University;Liaohe Petrochemical Company of China National Petroleum Corporation;

【通讯作者】 闫锋;

【机构】 辽宁石油化工大学石油化工学院; 中国石油天然气股份有限公司辽河石化分公司;

【摘要】 以草酸为原料,采用一步法合成了N-甲基吡咯烷酮草酸盐离子液体催化剂,将其应用于模拟油脱除碱性氮工艺。考察了离子液体催化剂反应时间、温度、剂油比、H2O2用量对喹啉脱除率的影响。实验结果表明:在反应温度为45℃,反应时间为40 min、剂油比为1∶10、无氧化剂条件下,喹啉脱除率可达98.59%,让离子液体重复使用4次后喹啉脱除率可达85.49%。

【Abstract】 N-methylpyrrolidone oxalate ionic liquid catalyst was synthesized by one-step method using oxalic acid as raw material, It is applied to simulate oil alkali removal sexual nitrogen process. The effects of reaction time, temperature, ratio of agent to oil and amount of H2O2 on the removal rate of quinoline were investigated. The results show that the removal rate of quinoline can reach 98.59% when the reaction temperature is 45 ℃, the reaction time is 40 min, the ratio of agent to oil is 1∶10, and the removal rate of quinoline can reach 85.49% after repeated use of ionic liquid for 4 times.

【基金】 国家科技重大专项(2016ZX05010-004-005)
  • 【文献出处】 精细石油化工 ,Speciality Petrochemicals , 编辑部邮箱 ,2024年03期
  • 【分类号】TE624.5
  • 【下载频次】47
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