【摘要】 化学工业的快速发展促进了全球的经济增长，但随着化工生产过程中化石能源的大量消耗，也带来无法忽视的环境污染和气候变化等问题。闵恩泽院士自1990年起，致力于绿色化学的导向性基础研究，在传统的石油化工领域引入和集成新材料、新工艺与新过程，主持和指导多项国家重大基础研究项目的实施，积累相关绿色化学的新科技知识，为绿色炼油和石化新工艺奠定了基础，形成了多个影响深远的绿色化工技术，有力地推动了石油化工绿色技术的发展。本文总结了近30年来在闵恩泽院士奠基的催化新材料及绿色化学新知识基础上形成的绿色化工技术实践案例：己内酰胺绿色生产技术、流化床过氧化氢技术、过氧化氢法制环氧丙烷成套技术及环己烯酯化加氢制环己酮绿色合成技术。这些凝练了催化材料与化学工程的创新实践取得的结果和经验将为新技术革新提供基础和借鉴。更多还原

【Abstract】 The rapid development of the chemical industry has contributed to global economic growth and improved people’s quality of life. However, the massive consumption of fossil fuels in the chemical production process has also caused environmental pollution and climate change that cannot be ignored. Academician Min Enze has been committed to directional fundamental research in green chemistry since 1990. He has introduced and integrated new materials, processes, and reaction pathways into the traditional petrochemical industry, led and guided the implementation of multiple major national basic research projects, accumulated new technological knowledge in green chemistry, laid the foundation for green refining and petrochemical new processes, and developed multiple influential green chemical technologies, effectively promoting the development of green technologies in the petrochemical industry. This article summarizes the green chemical technology practice cases formed on the basis of the catalytic new materials and green chemistry new knowledge laid by Academician Min Enze in the past 20 years, including the green production technology of caprolactam, fluidized bed hydrogen peroxide technology, complete technology of epoxy propane production by hydrogen peroxide method, and green synthesis technology of cyclohexene esterification and hydrogenation. These condensed innovative practices and experiences in catalytic materials and chemical engineering will provide a foundation and reference for us to carry out new technological innovations.更多还原