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纳米埃洛石-金属氧化物复合材料的制备与性能研究

Study on the preparation and properties of nano halloysite-metal oxide composite

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【作者】 刘达刘静邓泽斌赖升晖黄金灼王瑛赫袁光明

【Author】 Liu Da;Liu Jing;Deng Zebin;Lai Shenghui;Huang Jinzhuo;Wang Yinghe;Yuan Guangming;School of Materials Science and Engineering, Central South University of Forestry and Technology;

【通讯作者】 袁光明;

【机构】 中南林业科技大学材料科学与工程学院

【摘要】 利用单一方式去除甲醛效果差,采用物理吸附与催化相结合的方式,可起到优势互补的效果。以硅烷偶联剂(KH550)改性的纳米埃洛石(HNTs)为载体,MnO2、CuO和CeO2为催化剂制备了一种用于去除室内甲醛的埃洛石-金属氧化物复合材料。结果表明:Cu-Mn-Ce已负载至纳米埃洛石中;且纳米埃洛石的大孔径和Cu-Mn-Ce的高比表面积为复合材料提供了更利于吸附甲醛的孔结构;此外,Cu-Mn-Ce的负载为复合材料提供了可将甲醛催化转化成CO2和H2O的活性氧,经过24h后,复合材料在室温下的甲醛去除率为57.4%。因此,该方法制备的复合材料在室内除醛领域具有一定的研究潜能。

【Abstract】 The use of a single approach to remove formaldehyde is ineffective, and the use of a combination of physical adsorption and catalysis can provide complementary advantages.A nano halloysite-metal oxide composite for indoor formaldehyde removal was prepared using silane coupling agent(KH550)-modified nano halloysite(HNTs) as the carrier and MnO2,CuO,CeO2 as the catalysts.The results showed that Cu-Mn-Ce had been successfully loaded into nano halloysite, and the large pore size of nano halloysite and the high specific surface area of Cu-Mn-Ce provided the composite with a pore structure more conducive to the adsorption of formaldehyde.Moreover, the loading of Cu-Mn-Ce provided the composite with active oxygen that could catalytically convert formaldehyde into CO2 and H2O.After 24 hours at room-temperature, the formaldehyde removal rate was 57.4%.Therefore, the composite prepared by this method had certain research potential in the field of indoor formaldehyde removal.

【基金】 国家自然科学基金(32171708和31770606);国家重点研发计划项目(2019YFE0114600)
  • 【文献出处】 化工新型材料 ,New Chemical Materials , 编辑部邮箱 ,2024年S1期
  • 【分类号】TB332
  • 【下载频次】70
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