【摘要】 通过对苝酰亚胺的改性，合成了湾位双键官能团化、侧链为燕尾链的苝酰亚胺衍生物1,7-vinyl-PDI-EH。通过控制变量、优化合成反应条件，以反应浓度3.5 mg/mL在色谱纯级别（HPLC）四氢呋喃中反应2 h时，目标产物产率最高。进一步采用紫外可见分光光谱、荧光光谱以及浓度依赖光谱对其光物理性能和自组装行为进行表征，结果表明1,7-vinyl-PDI-EH在氯仿溶液中浓度达到1.1×10^-4 mol/L后随着浓度增大荧光淬灭，7.0×10^-4 mol/L时分子产生明显自组装。通过氯仿和甲醇体系的双扩散晶体培养，得到1,7-vinyl-PDI-EH晶体，其在结晶状态下仍有一定荧光性能。更多还原

【Abstract】 A new perylene diimide derivative called 1,7-vinyl-PDI-EH was synthesized, containing a double bond at the bay site and a swallow-tailed side chain at the imide site. The reaction conditions were optimized, and the highest yield of 1,7-vinyl-PDI-EH was achieved at a concentration of 3.5 mg/ml in HPLC-grade tetrahydrofuran with a reaction time of 2 hours. The photophysical properties and solution self-assembly behavior were characterized using UV-Vis and fluorescence spectroscopy. As the concentration increased above 1.1×10^-4 mol/L in chloroform solution, fluorescence quenching was observed, with the self-assembly concentration of 1,7-vinyl-PDI-EH determined to be 7.0×10^-4 mol/L. Crystals of 1,7-vinyl-PDI-EH were obtained using a double-diffusion method in a chloroform/methanol system and exhibited fluorescence in the crystalline state.更多还原