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光热驱动PS-PS@PDA偏心纳米马达的制备及运动性能研究

Preparation of Photothermal-Driven PS-PS@PDA Eccentric Nanomotors and Study on Their Motion Behavior

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【作者】 翟祥翔郭杰官建国罗明

【Author】 ZHAI Xiangxiang;GUO Jie;GUAN Jianguo;LUO Ming;State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology;International School of Materials Science and Engineering,Wuhan University of Technology;

【通讯作者】 罗明;

【机构】 武汉理工大学材料复合新技术国家重点实验室武汉理工大学材料科学与工程国际化示范学院

【摘要】 以聚苯乙烯(PS)纳米颗粒为模板,通过模板法制备了一种光热驱动聚苯乙烯-聚苯乙烯@聚多巴胺(PS-PS@PDA)偏心纳米马达,利用扫描电子显微镜、透射电子显微镜对其形貌结构进行了表征,并评价了其光热性能和运动性能。结果表明,PS-PS@PDA偏心纳米马达由1个挤出的PS小球和1个核壳结构PS@PDA大球组成,直径分别为(134.7±12.4) nm和(229.3±6.5) nm;在近红外激光照射下,纳米马达表现出良好的光热转换性能和光热稳定性;随着激光功率密度的增加,纳米马达的扩散系数逐渐增大,当功率密度为2.0 W·cm-2时,扩散系数达到15.57μm2·s-1,比布朗运动的扩散系数提高了约32倍;此外,纳米马达在不同的生物介质中依然能够维持高效驱动。

【Abstract】 Taking polystyrene(PS) nanoparticles as a template, we prepared photothermal-driven polystyrene-polystyrene@polydopamine(PS-PS@PDA) eccentric nanomotors by using a template method.Moreover, we characterized the morphology by scanning electron microscopy and transmission electron microscopy, and evaluated the photothermal performance and motion performance.The results show that PS-PS@PDA eccentric nanomotor consists of a small extruded PS pellet and a large core-shell PS@PDA with the diameter of(134.7±12.4) nm and(229.3±6.5) nm, respectively.The nanomotor exhibits good photothermal conversion performance and photothermal stability under near-infrared light irradiation.With the increase of the laser power density, the diffusion coefficient of the nanomoter increases gradually.When the power density is 2.0 W·cm-2,the diffusion coefficient reaches 15.57 μm2·s-1,which is about 32 times higher than that of Brownian motion.In addition, the nanomotor can still maintain efficient movement in various biological media.

【基金】 国家自然科学基金项目(22075222)
  • 【文献出处】 化学与生物工程 ,Chemistry & Bioengineering , 编辑部邮箱 ,2024年10期
  • 【分类号】TB383.1
  • 【下载频次】51
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