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烧结温度和造孔剂对沸石多孔陶瓷性能的影响

Effect of Sintering Temperature and Pore Forming Agent on the Properties of Zeolite Porous Ceramics

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【作者】 赖伟其段小云朱尧王斌宾衍辉马晓茜

【Author】 LAI Weiqi;DUAN Xiaoyun;ZHU Yao;WANG Bin;BIN Yanhui;MA Xiaoqian;Guangzhou Zhongdianlixin Thermal Power Co.Ltd.;School of Electric Power, South China University of Technology;

【机构】 广州中电荔新热电有限公司华南理工大学电力学院

【摘要】 将天然沸石应用到耐火材料领域中,以天然沸石为主要原材料、TiO2和WO3作为添加剂、活性炭作为造孔剂,采用部分烧结的方法制备多孔陶瓷。主要探讨了不同烧结温度(600、800和1 000℃)和活性炭比例(0、5%和10%)对多孔陶瓷的显气孔率、耐压强度、物相组成和微观形貌的影响。结果表明:烧结后试样的主要物相由TiO2、CaWO4和石英构成,试样的物相随温度升高没有显著的改变。当活性炭比例为10%、烧结温度为1 000℃时,试样具备最佳的物理性能,显气孔率为50.39%,耐压强度为3.78MPa。旨在为采用天然沸石制备多孔陶瓷提供有价值的理论指导。

【Abstract】 Natural zeolite was applied to the field of refractory materials, and porous ceramics were prepared by partial sintering with natural zeolite as the main raw materials, TiO2 and WO3 as additives, and activated carbon as pore making agents. The effects of different sintering temperatures(600, 800 and 1 000 ℃) and activated carbon ratios(0, 5% and 10%) on porosity, compressive strength, phase composition and micromorphology of porous ceramics were mainly discussed. The results showed that the main phase of the sample after sintering was composed of TiO2, CaWO4 and quartz, and the phase of the sample did not change significantly with the increase of temperature. When the proportion of activated carbon was 10% and the sintering temperature was 1 000 ℃, the sample showed the best physical properties, with a porosity of 50.39% and a compressive strength of 3.78 MPa. It aims to provide valuable theoretical guidance for the preparation of porous ceramics using natural zeolite.

【基金】 广州发展科技研发计划(T-2030201050)
  • 【文献出处】 工业加热 ,Industrial Heating , 编辑部邮箱 ,2024年02期
  • 【分类号】TQ174.1
  • 【下载频次】105
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