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高温下氮化硅陶瓷摩擦磨损性能的演变及机理研究

Evolution and Mechanism of Friction and Wear Properties of Silicon Nitride Ceramics at High Temperature

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【作者】 刘文进周国相杨治华贾德昌

【Author】 LIU Wenjin;ZHOU Guoxiang;YANG Zhihua;JIA Dechang;Institute for Advanced Ceramics, Harbin Institute of Technology;Chongqing Research Institute, Harbin Institute of Technology;

【通讯作者】 杨治华;

【机构】 哈尔滨工业大学特种陶瓷研究所哈尔滨工业大学重庆研究院

【摘要】 Si3N4陶瓷因具有耐高温、耐腐蚀、耐磨损、高硬度等特点,在高温耐磨损领域的应用备受关注。本文研究了高温下Si3N4陶瓷与C/SiC陶瓷或GH214合金摩擦时的平面摩擦磨损性能及磨损机理。结果表明:Si3N4陶瓷和C/SiC陶瓷对磨时,随着温度升高,摩擦系数先增大后减小;当温度为1 200℃时,Si3N4陶瓷平均摩擦系数低于0.4,且其磨损表面出现磨痕、磨粒和SiO2氧化膜,磨损形式主要为磨粒磨损和氧化磨损。Si3N4陶瓷与GH214合金对磨时,随着温度升高,摩擦系数增大,陶瓷样品表面出现明显的金属氧化物层,其磨损形式主要为粘着磨损和氧化磨损。Si3N4陶瓷与两种对磨材料摩擦时,氧化磨损均产生氧化膜并对Si3N4陶瓷均有保护和润滑作用,可有效减少Si3N4陶瓷基体的磨损,提高Si3N4陶瓷的磨损使用寿命。

【Abstract】 Si3N4 ceramics have attracted much attention in the field of high temperature wear resistance because of high temperature resistance, corrosion resistance, wear resistance and hardness. In this paper, the plane friction and wear properties and mechanism of Si3N4 ceramics when wearing with C/SiC ceramics or GH214 superalloy at high temperature were investigated. The results show that the friction coefficient of Si3N4 ceramics against C/SiC ceramics increases first and then decreases with the increase of temperature. The average friction coefficient of Si3N4 ceramics at 1 200 ℃ is lower than 0.4, and wear marks, wear particles and SiO2 oxide film appear on wear surface. The wear forms are mainly abrasive grain wear and oxidation wear. When Si3N4 ceramics and GH214 superalloy are worn against each other, the friction coefficient increases with the increase of temperature. Meanwhile, obvious metal oxide layer is formed on the surface of ceramic samples, so the wear forms are mainly adhesive wear and oxidation wear. During the friction process of Si3N4 ceramics and two kinds of friction materials, the oxide film produced by oxidation wear has protective and lubricating effects on Si3N4 ceramics, which can effectively reduce the wear of Si3N4 ceramics matrix and improve the wear life of Si3N4 ceramics.

  • 【文献出处】 硅酸盐通报 ,Bulletin of the Chinese Ceramic Society , 编辑部邮箱 ,2024年01期
  • 【分类号】TQ174.1
  • 【下载频次】79
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