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纳米纤维素基复合材料在锂硫电池中的应用研究进展

Research Progress in Application of Nano-Cellulose Based Composites in Lithium-Sulfur Batteries

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【作者】 黄少炎修慧娟王志雄樊莎王思敏邓自立李娜李金宝

【Author】 HUANG Shaoyan;XIU Huijuan;WANG Zhixiong;FAN Sha;WANG Simin;DENG Zili;LI Na;LI Jinbao;School of Light Industry Science and Engineering, Shaanxi University of Science and Technology;

【通讯作者】 李金宝;

【机构】 陕西科技大学轻工科学与工程学院

【摘要】 锂硫电池因具有高的理论比容量和能量密度,成为极具应用前景的下一代储能器件。纳米纤维素基材料因其独特的多孔网状结构和理化特性,在锂硫电池的开发研究中受到广泛关注。本文在简要介绍锂硫电池基本工作原理的基础上,分析了阻碍其商业化发展的问题和面临的挑战。针对纳米纤维素的独特结构和优异性能,重点综述了纳米纤维素基复合材料在锂硫电池中的最新研究进展,包括作为隔膜、阴极材料和其他组件等,有效缓解“穿梭效应”“体积膨胀”和“锂枝晶”等关键难题,明显提升了电池的电化学性能与使用寿命。此外,还介绍了纳米纤维素基复合材料在未来发展中亟待解决的问题,并对纤维素基锂硫电池器件的发展方向进行了展望。

【Abstract】 Lithium-sulfur battery has high theoretical specific capacity and energy density, which makes it a promising candidate as the next-generation energy storage device. In the research and development of lithium-sulfur batteries, nanocellulose-based materials have attracted extensive attention due to their unique network structure and the physicochemical properties. The present paper starts by introducing the basics of lithium-sulfur battery, and further analyzes the challenges hindering its commercialization. The paper also reviews the latest research of nanocellulose-based materials in lithium-sulfur batteries, from the perspectives of the unique structure and excellent performance of nanocellulose. It can be concluded that nanocellulose-based materials can serve as separators, cathode materials, and other components, and can alleviate critical problems is Li-S battries including ‘shuttle effect’, ‘volume expansion’ and ‘lithium dendrite’, and also significantly improve the electrochemical performance and service life. Finally, the challenges to nanocellulose-based composites and the outlook for cellulose-based lithium-sulfur batteries are discussed.

【基金】 浙江省重点研发计划项目(2022C02074)~~
  • 【分类号】TM912;TB332
  • 【下载频次】81
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