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顺北地区CO2/H2S气井管柱P110S腐蚀规律及主控因素研究

Research on the Corrosion Law and Main Control Factors of P110S in CO2/H2S Gas Well String in Shunbei Area

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【作者】 田疆袁键伍丽娟孟祥豪

【Author】 TIAN Jiang;YUAN Jian;WU Lijuan;MENG Xianghao;State Key Laboratory of Oil and Gas Reservoir Geology and Development Engineering,Chengdu University of Technology;Northwest Oilfield Branch of China Petroleum and Chemical Corporation;School of Petroleum Engineering,Changjiang University;

【通讯作者】 孟祥豪;

【机构】 油气藏地质及开发工程全国重点实验室(成都理工大学)中国石油化工股份有限公司西北油田分公司长江大学石油工程学院

【摘要】 为探究在CO2和H2S共存体系下顺北油气田井下温度、含水率、■分压比对P110S钢腐蚀速率的影响规律,利用高温高压微型反应釜开展了腐蚀模拟试验,并采取失重法计算腐蚀速率。利用JSM-IT300型扫描电子显微镜(SEM)与X射线衍射技术(XRD)对P110S钢材进行了腐蚀表征并对其生成物进行了深入的探究与剖析。研究结果表明:在1 MPa CO2分压和10 kPa H2S分压(■)分压比为100),含水率为15%时,P110S钢的腐蚀速率随着温度的上升先上升后降低,当温度达到70℃时,腐蚀速率达到极值0.658 mm/a;在1 MPa CO2分压和10 kPa H2S分压,温度为70℃时,P110S的钢腐蚀速率与含水率成正比,其腐蚀速率逐渐上升,直到含水率100%时腐蚀速率出现峰值1.730 mm/a;当温度为70℃,含水率为15%时,P110S钢腐蚀速率随着■分压比的增大先增大后减小。

【Abstract】 In order to investigate the effects of downhole temperature,water content,and ■ partial pressure ratio on the corrosion rate of P110S steel under the coexistence system of CO2 and H2S,corrosion simulation experiments were carried out by using high-temperature and high-pressure microreactors,and the weightlessness method was adopted to calculate the corrosion rate.Using JSM-IT300 scanning electron microscope(SEM) and X-ray diffraction(XRD) technology,the corrosion characterization of P110S steel and its generators were deeply explored and analyzed.The results show that,under the condition of1 MPa CO2 partial pressure and 10 kPa H2S partial pressure(■ partial pressure ratio of 100),and the moisture content of 15%,the corrosion rate of P110s steel first increased and then decreased with the increase of temperature,when the temperature goes to 70 ℃,the corrosion rate reaches an extreme value of 0.658 mm/a;under the condition of 1 MPa CO2 partial pressure and 10 kPa H2S partial pressure,and the temperature of 70 ℃,the corrosion rate of P110S steel is proportional to the moisture content,its corrosion rate gradually increased to the peak of 1.730 mm/a until the the moisture content reaches to100%;when the temperature goes to 70 ℃,and the water content reaches to 15%,the corrosion rate of P110s steel first increased and then decreased with the increase of ■ partial pressure ratio.

【关键词】 P110S■分压比腐蚀顺北油气田
【Key words】 P110S■ partial pressure ratiocorrosionShunbei region
【基金】 中国石化国内上游导向课题(YTBXD-SYGC-2024-3-02-004);国家自然科学基金(21974014)
  • 【文献出处】 表面工程与再制造 ,Surface Engineering & Remanufacturing , 编辑部邮箱 ,2024年06期
  • 【分类号】TE980
  • 【下载频次】12
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