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植物油精炼过程中缩水甘油酯和3-氯丙醇酯的形成及脱除研究进展

Research progress on formation and removal of glycidyl esters and 3-monochloropropane fatty acid esters in vegetable oil refining

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【作者】 刘壮; 刘萱; 罗日明; 陈东升; 杨博; 王卫飞; 蓝东明;

【Author】 LIU Zhuang;LIU Xuan;LUO Riming;CHEN Dongsheng;YANG Bo;WANG Weifei;LAN Dongming;College of Food Sciences and Engineering, South China University of Technology;Guangdong YUE-SHAN Special Nutrition Technology Co., Ltd.;COFCO ET (Xi′an) International Engineering Co., Ltd.;School of Bioscience and Bioengineering, South China University of Technology;

【通讯作者】 蓝东明;

【机构】 华南理工大学食品科学与工程学院; 广东粤膳特医营养科技有限公司; 中粮工科(西安)国际工程有限公司; 华南理工大学生物科学与工程学院;

【摘要】 缩水甘油酯(GEs)和3-氯丙醇酯(3-MCPDE)是植物油精炼过程中产生的主要污染物之一。GEs和3-MCPDE伴随食用油摄入人体后,经脂肪酶水解产生的缩水甘油和3-氯丙醇具有肾脏毒性和遗传毒性。植物油中GEs和3-MCPDE主要产生于油脂精炼脱臭工段,脱臭温度、脱臭时间对GEs和3-MCPDE的生成影响巨大。从油脂精炼加工过程中GEs和3-MCPDE的形成及脱除等方面进行了综述,指出脱色和脱臭工段可促进GEs和3-MCPDE的生成,当前可通过抑制及脱除其前体物质、优化植物油脱臭条件、脱除精炼油中的GEs及3-MCPDE等方式降低植物油中GEs和3-MCPDE含量。酶制剂具有安全、无污染等优点,通过酶法酯交换降低待脱臭油脂中的甘油二酯和甘油单酯,进而减少脱臭过程中GEs及3-MCPDE的生成是降低GEs和3-MCPDE的发展趋势。

【Abstract】 Glycidyl esters(GEs) and 3-monochloropropane fatty acid esters(3-MCPDE)are one of the main pollutants in the refining process of vegetable oil.GEs and 3-MCPDE are taken into human body with edible oil, hydrolyzed by human lipase, and the products glycidyl and 3-chloropropanol have nephrotoxicity and genotoxicity. GEs and 3-MCPDE in vegetable oil are mainly produced in the deodorization process of oil refining. Deodorization temperature and time have a great impact on the production of GEs and 3-MCPDE. The formation and removal of GEs and 3-MCPDE in the process of oil refining were reviewed, and it was pointed out that the decolorization and deodorization section promoted the formation of GEs and 3-MCPDE. The content of GEs and 3-MCPDE in vegetable oil could be reduced by inhibiting and removing their precursors, optimizing the deodorization conditions of vegetable oil, and removing GEs and 3-MCPDE from refined oil. Enzymes have the advantages of safety and non-pollution, and enzymatic transesterification is used to reduce diglyceride and monoglyceride in oil to be deodorized, thus reducing the formation of GEs and 3-MCPDE in the deodorization process will be the development trend to reduce GEs and 3-MCPDE.

【基金】 国家重点研发项目(2019YFD1002403);国家自然科学基金(31930084);国家杰出青年科学基金(31725022);佛山市南海区人才创新创业团队(201811070001)
  • 【文献出处】 中国油脂 ,China Oils and Fats , 编辑部邮箱 ,2023年03期
  • 【分类号】TS224.6
  • 【下载频次】605
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