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Sn诱导Al-4Cu合金中θ′相向θ相的相转变机制及其对合金高温强度的影响(英文)

Sn-induced phase transformation mechanism from θ′ to θ in Al-4Cu alloy and its influence on high temperature strength

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【作者】 李广敬潘星惠廖恒成郑基伟杨墨瞳钱龙杰陆丽珍东南大学

【Author】 Guang-jing LI;Xing-hui PAN;Heng-cheng LIAO;Ji-wei ZHENG;Mo-tong YANG;Long-jie QIAN;Li-zhen LU;Jiangsu Key Laboratory of Advanced Metallic Materials,School of Materials Science and Engineering, Southeast University;

【通讯作者】 廖恒成;

【机构】 材料科学与工程学院江苏省先进金属材料高技术研究重点实验室

【摘要】 通过显微组织观察和拉伸试验研究添加0.02%Sn(质量分数)对Al-4Cu合金在573 K高温热暴露过程(100 h)中θ′向θ相转变机制和高温强度的影响。研究结果表明,Sn微合金化能完全改变Al-4Cu合金在持久热暴露过程中θ′相向θ相的相转变机制。在未添加Sn的Al-4Cu合金中,棒状θ相在粗化后的盘状θ′相的表面形核和生长。然而,当添加少量Sn后,θ相首先在β-Sn颗粒上异质形核,然后形成粗大的针状相。由于Sn微合金化能提高Al-4Cu合金中θ′相的数密度并降低其尺寸,因此,Al-4Cu合金在T5状态下的室温和573 K高温下的屈服强度得到显著提高。然而,Sn微合金化能同时促进持久热暴露过程中θ′相向θ相的转变,导致Al-4Cu合金在热暴露后的高温(573 K)强度显著降低。

【Abstract】 The effects of 0.02 wt.% Sn addition to Al-4Cu alloy on the phase transformation mechanism from θ′ to θ phase during a long-time heat exposure at 573 K for 100 h and on high temperature strength were studied through microstructure observation and tensile test. It is found that Sn micro-alloying in Al-4Cu alloy completely changes the mechanism of θ′ → θ phase transformation during the long-time heat exposure. In the alloy without Sn addition, rod-like θ phase nucleates and grows on the surface of coarsened disc-like θ’ phase. However, with Sn-micro-alloying, θ phase firstly heterogeneously nucleates on β-Sn particles, and then grows into much coarser needle-like phase. Trace addition of Sn significantly increases the yield strength of T5-samples at both room temperature and 573 K, because addition of Sn increases the number density of θ′ particles and reduces its size. But, after the long-time heat exposure, the high temperature(573 K) strength of Al-4Cu alloy is severely degraded because Sn accelerates the phase transformation from θ′ to θ phase.

【基金】 supported by Jiangsu Key Laboratory for Advanced Metallic Materials, China (No. BM2007204);the Fundamental Research Funds for the Central Universities, China (No. 2242016k40011)
  • 【文献出处】 Transactions of Nonferrous Metals Society of China ,中国有色金属学报(英文版) , 编辑部邮箱 ,2023年09期
  • 【分类号】TG132.3
  • 【下载频次】172
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