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基于可调谐半导体激光吸收光谱的氧气浓度高灵敏度检测研究
Research on highly sensitive detection of oxygen concentrations based on tunable diode laser absorption spectroscopy
【摘要】 可调谐半导体激光吸收光谱(TDLAS)是近年发展起来的一种激光光谱气体检测技术,相比于常见的电化学、离子导电陶瓷等技术,其具有选择性强、灵敏度高、响应快、可在线测量、抗背景光谱干扰能力强等优点,适用于复杂环境中气体的长期在线检测。氧气(O2)是人类生存环境中的重要气体,O2浓度的检测在生产生活各个领域应用广泛、意义重大。基于此,本文采用TDLAS技术对空气中的O2进行高灵敏度测量。采用输出波长为760 nm的半导体激光器作为光源,直接吸收光谱法获得环境中的氧气浓度为20.56%,最小检测极限为5.53×10-3。在波长调制方法中,优化了激光波长调制深度,得到了完整的二次谐波波形,可用于标定氧气浓度。此系统的信噪比为380.74,最小检测极限约为540×10-6。本文的传感系统具有良好的O2检测能力,可广泛用于各个领域中的O2浓度检测。
【Abstract】 Tunable Diode Laser Absorption Spectroscopy (TDLAS) is a recently developed laser spectral gas detection technology.Compared with common oxygen sensors such as electrochemical devices and ionic conductive ceramics,TDLAS has the advantages of high selectivity and sensitivity,fast response,on-line measurement and strong anti-background spectral interference ability.Oxygen (O2) is an important gas in habitable environments and is greatly significant to industrial production and human life,and the detection of O2 concentration is also widely used in these fields.Based on this,we adopt TDLAS technology to carry out high sensitivity measurements of O2 in air.Using a semiconductor laser with an output wavelength of 760 nm as the light source,the oxygen concentration in the environment is 20.56% by direct absorption spectroscopy,and the minimum detection limit is 5.53×10-3.In the wavelength modulation spectroscopy method,the laser wavelength modulation depth is optimized to obtain a complete second harmonic waveform,which can be used to calibrate the oxygen concentration.The SNR of the system is 380.74,and the minimum detection limit is about 540×10-6.The system realized in this paper has good oxygen detection ability and can be widely used in various fields of oxygen concentration detection.
【Key words】 TDLAS; Oxygen (O2) concentration detection; direct measurement; wavelength modulation; semiconductor laser;
- 【文献出处】 中国光学(中英文) ,Chinese Optics , 编辑部邮箱 ,2023年01期
- 【分类号】O657.38
- 【下载频次】54