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湘中矿集区钨与锑-金成因联系探讨:来自曹家坝钨矿床和龙山锑金矿床Sr-Nd-H-O同位素的制约

Discussion of the genetic relations between W and Sb-Au mineralization of Xiangzhong ore district: Constraints from Sr-Nd-H-O isotopic compositions of the Caojiaba W and Longshan Sb-Au deposits

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【作者】 张志远谢桂青袁亮

【Author】 ZHANG ZhiYuan;XIE GuiQing;YUAN Liang;Hebei Key Laboratory of Strategic Critical Mineral Resources,Hebei GEO University;School of Earth Sciences and Resources,China University of Geosciences;MNR Key Laboratory for Exploration Theory & Technology of Critical Mineral Resources;Hunan Xinlong Mining Co.Ltd.;

【通讯作者】 谢桂青;

【机构】 河北地质大学,河北省战略性关键矿产资源重点实验室中国地质大学地球科学与资源学院自然资源部战略性金属矿产找矿理论与技术重点实验室湖南新龙矿业有限责任公司

【摘要】 湘中是全球最大的锑金矿集区,近年来又陆续探明了一批钨矿床,但这些钨矿和锑金矿之间的关系目前尚不明确。曹家坝钨矿床是目前该矿集区内规模最大的钨矿床(19.03Mt@0.37%WO3),矿体与矽卡岩密切共生,成矿作用划分为矽卡岩阶段、退化蚀变阶段和石英-白钨矿-硫化物阶段。不同阶段白钨矿δ18OV-SMOW变化范围为6.0‰~7.9‰,δDV-SMOW变化范围为-79.1‰~-68.9‰,对应的δ18OH2O变化范围为3.3‰~5.2‰。白钨矿(87Sr/86Sr)t变化范围为0.72215~0.73049,εNd(t)变化范围为-12.8~-10.6。龙山锑金矿床是矿集区内发育的大型脉状锑金矿床(4.2Mt@3.4%Sb和3.7g/t Au),矿体赋存在震旦系江口组板岩中,发育两个世代的白钨矿与辉锑矿共生。白钨矿δ18OV-SMOW变化范围为5.4‰~9.0‰,δDV-SMOW变化范围为-72.9‰~-60.2‰,对应的δ18OH2O变化范围为3.1‰~6.7‰。Sr-Nd-H-O多元同位素特征显示,曹家坝钨矿床的成矿物质和成矿流体以岩浆来源为主,龙山锑金矿床有岩浆流体参与成矿,两者均有少量板溪群基底地层和大气降水的加入。综合本次及前人研究成果,曹家坝钨矿床和龙山锑金矿床具有成因联系,二者均是湘中矿集区晚三叠世岩浆热液W-Sb-Au成矿系统的重要组成部分。

【Abstract】 The Xiangzhong has been the largest Sb-Au ore district in the world so far. In recent years, a number of W deposits have been discovered in this area, however, the relationship between the W and Sb-Au mineralization is still unclear. The Caojiaba deposit is the largest W deposit in the ore district up to now(19.03Mt@ 0.37% WO3), whose ore bodies are closely related to skarn, i.e., its mineralization is characterized by an early prograde skarn overprinted by a retrograde assemblage, and then by quartz-scheelite-sulfide veins. Geochemically, the δ18OV-SMOW and δDV-SMOW of scheelites formed at different stages of the deposit range from 6.0‰ to 7.9‰ and from-79.1‰ to-68.9‰, respectively, with corresponding δ18OH2O values varying from 3.3‰ to 5.2‰; while the(87Sr/86Sr)t and εNd(t) of the scheelites range from 0.72215 to 0.73049, from-12.8 to-10.6, respectively. The Longshan deposit is a large lode Sb-Au deposit in the ore district(4.2Mt@ 3.4% Sb and 3.7g/t Au). The ore body is hosted within Sinian Jiangkou Formation slate, and two generations of scheelites are associated with stibnite. The δ18OV-SMOW and δDV-SMOW of scheelite range from 5.4‰ to 9.0‰ and from-72.9‰ to-60.2‰, respectively, with corresponding δ18OH2O values ranging from 3.1‰ to 6.7‰. The Sr-Nd-H-O isotopic compositions show that ore-forming material and fluid of the Caojiaba tungsten deposit were mainly derived from the magmatic-hydrothermal system. The magmatic fluid was involved in the mineralization of the Longshan Sb-Au deposit, and minor Banxi Group basement strata and meteoric water were involved in the ore-forming process of the Caojiaba and Longshan deposits. Based on the results of this study and previous work, the Caojiaba W deposit and the Longshan Sb-Au deposit are genetically related to each other, i.e., both of them are important components of the Late Triassic magmatic hydrothermal W-Sb-Au metallogenic system in the Xiangzhong ore district.

【基金】 国家自然科学基金项目(41925011、42002094)资助
  • 【文献出处】 岩石学报 ,Acta Petrologica Sinica , 编辑部邮箱 ,2023年06期
  • 【分类号】P618.2
  • 【下载频次】71
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