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低温下低动静刚度天然橡胶胶料的配方研究
Research on Formula of NR Compound with Low Static and Dynamic Stiffness at Low Temperature
【摘要】 对低温下低动静刚度天然橡胶(NR)胶料的配方进行研究。结果表明:N-苯基马来酰亚胺(N-PMI)具有较高的反应活性,可在混炼或/和硫化时通过加成反应键接到NR分子主链上,降低NR分子链的规整性,从而明显降低NR的低温结晶性;添加N-PMI的硫黄硫化体系NR胶料和过氧化物硫化体系NR胶料在-40℃时的弹性模量和硬度均较低,采用这两种硫化体系NR胶料的制品在低温下表现出低动静刚度,这两种硫化体系NR胶料的N-PMI最佳用量均为5份。
【Abstract】 The formula of natural rubber(NR) compound with low static and dynamic stiffness at low temperatures was studied. The results showed that N-phenyl maleimide imide(N-PMI) had high reactivity and could be bonded to the main chain of NR molecules through addition reaction during mixing or/and vulcanization which reduced the regularity of NR molecular chain,and thus significantly reduced the lowtemperature crystallinity of NR. The NR compounds with N-PMI cured with sulfur vulcanization system or peroxide vulcanization system had low elastic modulus and hardness at-40 ℃. The products using these two NR compounds exhibited low static and dynamic stiffnesses at low temperatures,and the optimal dosage of N-PMI for both NR compounds was 5 phr.
【Key words】 NR; N-phenyl maleimide imide; low temperature crystallization; low static and dynamic stiffness;
- 【文献出处】 橡胶工业 ,China Rubber Industry , 编辑部邮箱 ,2023年08期
- 【分类号】TQ332
- 【下载频次】5