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硫化条件对天然橡胶/反式丁戊橡胶并用胶应用性能的影响

Effect of vulcanization conditions on properties of NR/TBIR blends

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【作者】 王浩; 李兰阁; 赵涛; 葛怀涛; 王日国; 翟红莲; 栾波;

【Author】 WANG Hao;LI Lange;ZHAO Tao;GE Huaitao;WANG Riguo;ZHAI Honglian;LUAN Bo;Shandong Chambroad Holding Co.,Ltd.;Shandong Huaju Polymer Materials Co.,Ltd.;Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization;

【机构】 山东京博控股集团有限公司; 山东华聚高分子材料有限公司; 山东省烯烃催化与聚合重点实验室;

【摘要】 研究了硫化温度和硫化时间对天然橡胶(NR)和NR/反式丁戊橡胶(TBIR)并用胶应用性能的影响。结果表明,在相同的硫化温度下,NR与NR/TBIR并用胶的焦烧时间、工艺正硫化时间和交联密度几乎一致。对比140℃、150℃和160℃硫化温度下NR和NR/TBIR硫化胶的性能,NR/TBIR并用胶在160℃下硫化时磨耗性能和滚动阻力优势最大,150℃硫化时疲劳性能优势最大。对比160℃下的硫化时间,发现其变化不会明显影响TBIR在NR体系中的磨耗性能、滚动阻力和疲劳性能优势的发挥。

【Abstract】 The effects of vulcanization temperature and time on the application properties of NR and NR/TBIR blends were studied.The results showed that, the scorch time, optimum curing time and crosslinking density of NR and NR/TBIR blends were almost the same at the same curing temperature.The properties of NR and NR/TBIR vulcanizated at 140 ℃,150 ℃ and 160 ℃ were investigated.Compared with NR vulcanizates, NR/TBIR vulcanized at 160 ℃ showed the greatest advantages in wear resistance and rolling resistance.And the fatigue resistance of NR/TBIR vulcanized at 150 ℃ was best.It was also found that the change of vulcanization time did not significantly affect the advantages of NR/TBIR vulcanizates in the wear resistance, rolling resistance and fatigue resistance compared with NR vulcanizates.

【基金】 国家重点研发计划项目(SQ2022YFB3700063);山东省重大科技创新工程项目(2021CXGC010901)
  • 【分类号】TQ330.1
  • 【下载频次】20
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