【摘要】 以丙烯酸羟丙酯（HPAA）、丙烯酸（AA）及甲基丙烯酸十二氟庚酯（G04）为原料，制备了一种溶液共聚型全氟羟基丙烯酸树脂（PFHA），用傅立叶变换红外光谱仪（FT-IR）对PFHA进行了结构表征。以PFHA、油水两用型钛白粉和季铵基硅溶胶包覆纳米银（QAg-SiO₂）等为主要成分配制了溶剂型含氟丙烯酸涂料，分别考察了树脂羟基含量、纳米二氧化钛和QAg-SiO₂含量对涂层性能的影响。结果表明：当树脂羟基含量为3.3%、涂料中TiO₂和QAg-SiO₂的含量分别为25%和10%时（均为质量分数），涂层的水接触角为114°，硬度为3H，附着力为1级，且经硫酸盐还原菌浸泡168 h后无腐蚀，具有优良的物理性能与防腐抗菌性能。更多还原

【Abstract】 A solution copolymerized perfluoro hydroxyl acrylic resin（PFHA） was prepared by free radical polymerization using hydroxypropyl acrylate（HPAA）,acrylic acid（AA）and dodecfluoroheptyl methacrylate（G04）. The PFHA structure was characterized by Fourier transform infrared spectroscopy（FT-IR）. Solvent fluorine-containing coatings were prepared with fluorine-containing acrylic resin（PFHA）,oil-water titanium dioxide（TiO₂）and quaternary ammonium silica sol coated nano silver（QAg-SiO₂）. The effects of hydroxyl content in resin,contents of nano titanium dioxide and QAg-SiO₂ on the film properties were investigated. The results showed that,when the hydroxyl value of the resin was 3. 3% and the content of TiO₂ and QAg-SiO₂ were 25% and 10% respectively,the coating had excellent physical properties,corrosion and bacterial resistance with the hydrophobic angle of 114°,hardness of 3H,adhesion of grade 1,and there was no corrosion after being soaked in sulfate reducing bacteria for 168 h.更多还原